Carbonized seawater cement slurries for offshore deep cement mixing: Carbonation mechanism, strength enhancement and microstructure evolution

Abstract

Seawater cement slurry (SCS) is a commonly used binder in offshore deep cement mixing (DCM) construction. Seawater cement slurries are usually prepared before they are grouted into the seabed and mixed with marine clay. The aim of this study is to explore the feasibility of applying carbonation technology to fabricate SCS suitable for offshore DCM while achieving carbon sequestration and obtaining better mechanical properties for stabilised marine sediments.

This study demonstrated that after appropriate carbonation, carbonized SCS can be used in DCM to replace conventional SCS. Short-term carbonation promotes cement dissolution and hydration rates under seawater conditions rich in magnesium, calcium, and other inorganic ions. The carbonates include calcite, vaterite and amorphous carbonates, which provide additional nucleation sites for the hydration of SCS, resulting in an increment for amorphous CS(A)H gel with a dense pore structure and binding interaction with soil particles. After carbonation with 20 % CO2 for 5 min (0.5 wt% of cement), the UCS and secant modulus of cement-soil mixtures by 15.7 % and 111 % at the age of 1 day, and by 6.82 % and 10 % at the age of 28 days when treating marine clay with 80 % moisture content at a dosage of 260 kg/m³.