Zhengzhong Cheng, Qian Zhang, Dr. Zhifang Li, Dr. Jinxing Cui., Jiao Zhao, Ruichao Yang, Dr. Yuanyuan Ma, Zhen Zhang, Qi Wang, Prof. Changlong Yang
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引用次数: 0
Abstract
Microporous zeolite is commonly employed as the catalyst for selective catalytic reduction of NOx using NH3 as reducing agent (NH3-SCR) because of its strong acidity and exceptional hydrothermal stability. However, the channel of microporous zeolite limits mass transfer under low temperature. Hierarchical porous molecular sieves can overcome the above imperfections. Hierarchical pore (microporous/mesoporous/macroporous) ZSM-5 molecular sieves were prepared using polystyrene(PS) microspheres with different particle size as the hard templates and then the ion exchange method was utilized to introduce the active components Ce, Cu, and La. In addition, the effect of PS microspheres with different size and H2O+SO2 on denitrification performance was also investigated. The results exhibited that the specific surface area of the hierarchical pore ZSM-5 was the smallest when the size of polystyrene microspheres was the largest. The NOx conversion of all supported hierarchical porous catalysts is more than that of supported microporous ZSM-5 catalyst in the low temperature (200 °C), which was because that the presence of the mesopores favored diffusion-control in the low temperature, expediting the reactant transport. Furthermore, the supported hierarchical pore ZSM-5 catalyst exhibited excellent denitrification performance in a wide temperature range of 250–500 °C (the conversion of NOx exceeded 80 % and the N2 selectivity was approaching 100 %). More importantly, the supported hierarchical pore ZSM-5 catalyst demonstrated notably superior water and SO2 resistance in comparison to the supported micropore ZSM-5 catalyst.
期刊介绍:
ChemistrySelect is the latest journal from ChemPubSoc Europe and Wiley-VCH. It offers researchers a quality society-owned journal in which to publish their work in all areas of chemistry. Manuscripts are evaluated by active researchers to ensure they add meaningfully to the scientific literature, and those accepted are processed quickly to ensure rapid online publication.