Biodegradable packaging paper derived from chitosan-based composite barrier coating for agricultural products preservation

Abstract

Development of green packaging materials is essential to replace traditional plastics in fresh agricultural products preservation. Herein, a coated paper was designed by applying chitosan-based composite coating on paper substrate through a facile automatic coating method. The hydroxypropyl trimethyl ammonium chloride chitosan (HACC) was obtained by direct quaternization via the introduction of hydroxypropyl trimethyl ammonium chloride into the amino group of chitosan, then mixed with polyvinyl alcohol (PVA) to prepare the HACC/PVA coating. Accordingly, the key performance of coated paper were improved ascribed to the synergy effect of HACC/PVA coating and paper substrate. In particular, the minimum oxygen permeability of the coated paper could reach to 0.87 × 10⁻¹³ cm³·cm/cm²·s·Pa, and the optimum water vapor permeability and tensile strength of HACC/PVA coated paper was 0.75 × 10⁻¹² g·cm/cm²·s·Pa and 6.88 kN/m, respectively. The coated paper used as packaging material not only reduced weight loss ratio of strawberry and greengrocery, but also exhibited lower chromatic aberration and better sensory evaluation, indicating a favorable effect on fruit and vegetable storage. Taken together, the designed eco-friendly coated paper has shown tremendous potential for green and biodegradable packaging material in agricultural products preservation.