Alkali-Stable Metal-Organic Frameworks with Enhanced Electroconductivity for Black-Brown Electrochromic Energy Storage Smart Window.

Abstract

Metal-organic frameworks (MOFs) deliver potential applications in electrochromism and energy storage. However, the poor intrinsic conductivity of MOFs in electrolytes seriously hampers the development of the above-mentioned electrochemical applications, especially in one MOF electrode. Herein, a new Ni-based MOF (denoted Ni-DPNDI) is proposed with enhanced conductivity by π-delocalized DPNDI connectors. Predictably, the obtained Ni-DPNDI MOF achieves a conductivity of up to 4.63 S∙m^-1 at 300 K. Profiting from its unique electronic structure, the Ni-DPNDI MOF delivers excellent electrochromic and energy storage performance with a great optical modulation (60.8%), a fast switching speed (t_c = 7.9 s and t_b = 6.4 s), a moderate specific capacitance (25.3 mAh·g^-1) and good cycle stability over 2000 times. Meanwhile, energy storage capacity is visual by the coloration states of Ni-DPNDI film. As a proof of the potential application, a large-area (100 cm²) electrochromic energy storage smart window is further designed and displayed. The strategy provides an interesting alternative to porous multifunctional materials for the new generation of electronic devices with diverse applications.