Hugo Olvera-Vargas , Oscar Andrés Jaramillo-Quintero , Luis Darío Alarcón León , Orlando Castro-Ocampo , Christian A. Celaya , Marina E. Rincón , Jesús Muñiz
{"title":"Green synthesis of glycolic acid through the electrocatalytic reduction of oxalic acid over black TiO2: An experimental and theoretical study","authors":"Hugo Olvera-Vargas , Oscar Andrés Jaramillo-Quintero , Luis Darío Alarcón León , Orlando Castro-Ocampo , Christian A. Celaya , Marina E. Rincón , Jesús Muñiz","doi":"10.1016/j.jechem.2024.09.011","DOIUrl":null,"url":null,"abstract":"<div><div>Herein, we present the electrocatalytic four-electron hydrogenation of oxalic acid into glycolic acid using black TiO<sub>2</sub> as an electrocatalyst. Oxalic acid is an abundant compound found in several sources of organic waste. The results showed a high selectivity of black TiO<sub>2</sub> toward glycolic acid, with the formation of glyoxylic acid being the rate-limiting step (glyoxylic acid is the two-electron intermediate). The highest Faradaic efficiency (FE) of 69.6% ± 8.3% was achieved at 10.2 mA cm<sup>−2</sup> in 4 h of electrolysis using an H-type cell operated at room temperature, with 50.2% ± 3.8% of oxalic acid conversion (degradation kinetic constant <em>k</em> = 0.0042 ± 0.0001 min<sup>−1</sup>), 58.8% ± 7.0% of reaction yield and 1.2 ± 0.18 g L<sup>−1</sup> of glycolic acid production. A theoretical model of black TiO<sub>2</sub> coming from anatase TiO<sub>2</sub> was implemented by introducing Ti<sup>3+</sup> defects, which gave black TiO<sub>2</sub> the theoretical capability to easily transform oxalic acid into glycolic acid as experimentally observed. The reaction mechanism was supported and described in detail by density functional theory calculations, which revealed that surface Ti<sup>3+</sup> states were the main catalytic sites. This is the first time that a detailed step-by-step mechanism at the atomic level has been proposed for this electrocatalytic reaction, which represents a valuable contribution to the understanding of this process of high energy/environmental interest. This is also the first time that black TiO<sub>2</sub> has been used as an electrocatalyst for this sustainable process.</div></div>","PeriodicalId":15728,"journal":{"name":"Journal of Energy Chemistry","volume":"100 ","pages":"Pages 544-556"},"PeriodicalIF":13.1000,"publicationDate":"2024-09-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Energy Chemistry","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2095495624006326","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"Energy","Score":null,"Total":0}
引用次数: 0
Abstract
Herein, we present the electrocatalytic four-electron hydrogenation of oxalic acid into glycolic acid using black TiO2 as an electrocatalyst. Oxalic acid is an abundant compound found in several sources of organic waste. The results showed a high selectivity of black TiO2 toward glycolic acid, with the formation of glyoxylic acid being the rate-limiting step (glyoxylic acid is the two-electron intermediate). The highest Faradaic efficiency (FE) of 69.6% ± 8.3% was achieved at 10.2 mA cm−2 in 4 h of electrolysis using an H-type cell operated at room temperature, with 50.2% ± 3.8% of oxalic acid conversion (degradation kinetic constant k = 0.0042 ± 0.0001 min−1), 58.8% ± 7.0% of reaction yield and 1.2 ± 0.18 g L−1 of glycolic acid production. A theoretical model of black TiO2 coming from anatase TiO2 was implemented by introducing Ti3+ defects, which gave black TiO2 the theoretical capability to easily transform oxalic acid into glycolic acid as experimentally observed. The reaction mechanism was supported and described in detail by density functional theory calculations, which revealed that surface Ti3+ states were the main catalytic sites. This is the first time that a detailed step-by-step mechanism at the atomic level has been proposed for this electrocatalytic reaction, which represents a valuable contribution to the understanding of this process of high energy/environmental interest. This is also the first time that black TiO2 has been used as an electrocatalyst for this sustainable process.
期刊介绍:
The Journal of Energy Chemistry, the official publication of Science Press and the Dalian Institute of Chemical Physics, Chinese Academy of Sciences, serves as a platform for reporting creative research and innovative applications in energy chemistry. It mainly reports on creative researches and innovative applications of chemical conversions of fossil energy, carbon dioxide, electrochemical energy and hydrogen energy, as well as the conversions of biomass and solar energy related with chemical issues to promote academic exchanges in the field of energy chemistry and to accelerate the exploration, research and development of energy science and technologies.
This journal focuses on original research papers covering various topics within energy chemistry worldwide, including:
Optimized utilization of fossil energy
Hydrogen energy
Conversion and storage of electrochemical energy
Capture, storage, and chemical conversion of carbon dioxide
Materials and nanotechnologies for energy conversion and storage
Chemistry in biomass conversion
Chemistry in the utilization of solar energy