Highly active Ti3C2Tx MXene nanoribbons@AuPt bimetallic nanozyme constructed in a “two birds with one stone” manner for colorimetric sensing of dipterex
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引用次数: 0
Abstract
The bimetallic nanoparticles have received significant attention in the field of colorimetric sensing, while the majority of the previous methods for synthesizing such nanoparticles typically require the use of reducers and involve highly harsh synthesis conditions. In this work, the AuPt bimetallic nanoparticles (AuPtNPs) decorated Ti3C2TxNR nanohybrid (Ti3C2TxNR@AuPt) was firstly synthesized in a “two birds with one stone” manner. Innovatively, during the synthesis process, Ti3C2TxNR served as both reducing agent and supporting agent to prevent aggregation of bimetallic nanoparticles. Due to the good synergistic effect of AuPtNPs and the strong metal-support interaction between AuPtNPs and Ti3C2TxNR, the as-prepared Ti3C2TxNR@AuPt exhibited boosted peroxidase (POD)-like activity. In advantage of the exceptional POD-like activity, a cost-effective and sensitive colorimetric sensing platform was fabricated for dipterex detection with a broad linearity of 1.0 ng mL−1-1.0 μg mL−1 and a low detection limit (0.479 ng mL−1). The detection of dipterex in insecticide samples also yielded favorable recoveries. Moreover, this approach provided a convenient and effective strategy to design and develop novel nanozymes via a “two birds with one stone” strategy.
期刊介绍:
Talanta provides a forum for the publication of original research papers, short communications, and critical reviews in all branches of pure and applied analytical chemistry. Papers are evaluated based on established guidelines, including the fundamental nature of the study, scientific novelty, substantial improvement or advantage over existing technology or methods, and demonstrated analytical applicability. Original research papers on fundamental studies, and on novel sensor and instrumentation developments, are encouraged. Novel or improved applications in areas such as clinical and biological chemistry, environmental analysis, geochemistry, materials science and engineering, and analytical platforms for omics development are welcome.
Analytical performance of methods should be determined, including interference and matrix effects, and methods should be validated by comparison with a standard method, or analysis of a certified reference material. Simple spiking recoveries may not be sufficient. The developed method should especially comprise information on selectivity, sensitivity, detection limits, accuracy, and reliability. However, applying official validation or robustness studies to a routine method or technique does not necessarily constitute novelty. Proper statistical treatment of the data should be provided. Relevant literature should be cited, including related publications by the authors, and authors should discuss how their proposed methodology compares with previously reported methods.