Carbene-Catalyzed [3 + 3] Annulation of Enals and Vinyl Sulfoxonium Ylides

IF 3.3 2区化学 Q1 CHEMISTRY, ORGANIC

The Journal of Organic Chemistry Pub Date : 2024-09-25 DOI:10.1021/acs.joc.4c01587

Siru Feng, Hailong Zhang, Jinhua Liu, Dongping Shi, Weiqi Yang, Haibin Zhu, Xiaoxiang Zhang, Zhenqian Fu

引用次数: 0

Abstract

Carbene-catalyzed [3 + 3] annulation of enals and vinyl sulfoxonium ylides has been demonstrated. This method efficiently synthesizes a range of 2-sulfenylidene-3-cyclohexen-1-ones with high atom economy. Notably, the presence of the sulfoxonium ylide moiety in the obtained products significantly enhances their potential for further synthetic transformations.

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碳催化烯醛和乙烯基锍酰化物的 [3 + 3] 嵌合反应

证明了碳催化烯醛和乙烯基锍酰化物的[3 + 3]环化反应。该方法能高效合成一系列 2-亚磺酰基-3-环己烯-1-酮，且原子经济性高。值得注意的是，所得产物中存在的乙烯砜酰基大大提高了其进一步合成转化的潜力。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

The Journal of Organic Chemistry 化学-有机化学

CiteScore

6.20

自引率

11.10%

发文量

1467

审稿时长

2 months

期刊介绍： The Journal of Organic Chemistry welcomes original contributions of fundamental research in all branches of the theory and practice of organic chemistry. In selecting manuscripts for publication, the editors place emphasis on the quality and novelty of the work, as well as the breadth of interest to the organic chemistry community.