TexSe1–x Shortwave Infrared Photodiode Arrays with Monolithic Integration

IF 11.3 1区化学 Q1 CHEMISTRY, PHYSICAL

ACS Catalysis Pub Date : 2024-09-26 DOI:10.1021/acs.nanolett.4c03728

Meng Peng, Yuming He, Yuxuan Hu, Zunyu Liu, Xinyi Chen, Zhiqiang Liu, Junrui Yang, Maohua Chen, Weijie Liu, Feng Wu, Luying Li, Jiangnan Dai, Changqing Chen, Jungang He, Long Hu, Chao Chen, Jiang Tang

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引用次数: 0

Abstract

Te_xSe_1–x shortwave infrared (SWIR) photodetectors show promise for monolithic integration with readout integrated circuits (ROIC), making it a potential alternative to conventional expensive SWIR photodetectors. However, challenges such as a high dark current density and insufficient detection performance hinder their application in large-scale monolithic integration. Herein, we develop a ZnO/Te_xSe_1–x heterojunction photodiode and synergistically address the interfacial elemental diffusion and dangling bonds via inserting a well-selected 0.3 nm amorphous TeO₂ interfacial layer. The optimized device achieves a reduced dark current density of −3.5 × 10^–5 A cm^–2 at −10 mV, a broad response from 300 to 1700 nm, a room-temperature detectivity exceeding 2.03 × 10¹¹ Jones, and a 3 dB bandwidth of 173 kHz. Furthermore, for the first time, we monolithically integrate the Te_xSe_1–x photodiodes on ROIC (64 × 64 pixels) with the largest-scale array among all Te_xSe_1–x-based detectors. Finally, we demonstrate its applications in transmission imaging and substance identification.

Abstract Image

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单片集成的 TexSe1-x 短波红外线光电二极管阵列

TexSe1-x 短波红外（SWIR）光电探测器有望与读出集成电路（ROIC）实现单片集成，成为传统昂贵的 SWIR 光电探测器的潜在替代品。然而，高暗电流密度和探测性能不足等挑战阻碍了其在大规模单片集成中的应用。在此，我们开发了一种 ZnO/TexSe1-x 异质结光电二极管，并通过插入精心挑选的 0.3 纳米非晶 TeO2 界面层，协同解决了界面元素扩散和悬空键问题。优化后的器件在 -10 mV 时的暗电流密度降低到 -3.5 × 10-5 A cm-2，响应范围从 300 纳米到 1700 纳米，室温检测率超过 2.03 × 1011 Jones，3 dB 带宽达到 173 kHz。此外，我们还首次在 ROIC（64 × 64 像素）上单片集成了 TexSe1-x 光电二极管，是所有基于 TexSe1-x 的探测器中规模最大的阵列。最后，我们展示了其在透射成像和物质识别方面的应用。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

ACS Catalysis CHEMISTRY, PHYSICAL-

CiteScore

20.80

自引率

6.20%

发文量

1253

审稿时长

1.5 months

期刊介绍： ACS Catalysis is an esteemed journal that publishes original research in the fields of heterogeneous catalysis, molecular catalysis, and biocatalysis. It offers broad coverage across diverse areas such as life sciences, organometallics and synthesis, photochemistry and electrochemistry, drug discovery and synthesis, materials science, environmental protection, polymer discovery and synthesis, and energy and fuels. The scope of the journal is to showcase innovative work in various aspects of catalysis. This includes new reactions and novel synthetic approaches utilizing known catalysts, the discovery or modification of new catalysts, elucidation of catalytic mechanisms through cutting-edge investigations, practical enhancements of existing processes, as well as conceptual advances in the field. Contributions to ACS Catalysis can encompass both experimental and theoretical research focused on catalytic molecules, macromolecules, and materials that exhibit catalytic turnover.