{"title":"Oxygen reduction reaction on Ag nanocatalysts prepared by the microemulsion method","authors":"","doi":"10.1016/j.electacta.2024.145098","DOIUrl":null,"url":null,"abstract":"<div><div>The microemulsion (water-in-oil) method is used to prepare novel silver catalysts onto three different carbon supports (multi-walled carbon nanotubes (MWCNT), mesoporous carbon (MC) and Vulcan carbon (C)). It allows to control the Ag particle growth and produces particles that range between 2 and 3 nm. The Ag-based catalysts are characterised by scanning transmission electron microscopy (STEM) with energy-dispersive X-ray spectroscopy (EDS). The electrocatalytic activity towards the oxygen reduction reaction (ORR) in 0.1 M KOH is studied using the rotating disc electrode method. High-angle annular dark-field (HAADF) STEM images reveal the Ag particle size range between 1.8 and 2.4 nm, and the EDS mapping shows uniform Ag distribution on the substrates used. Ag1/MC (two-step synthesis) and Ag2/MC (one-step synthesis) catalysts prepared onto the MC support show the highest mass activity of 30–37 A g<sup>−1</sup>. The two-step synthesis method is preferred to prepare Ag/MWCNT and Ag/C catalysts. The mass activity of the Ag1/MWCNT catalyst is more than two times higher than that of Ag2/MWCNT. Ag1/MWCNT shows the highest electrochemical stability after the accelerated durability test, with only a 6 mV shift in half-wave potential. The microemulsion method is very promising for the production of highly stable Ag-based catalysts with Ag particles smaller than 3 nm in size.</div></div>","PeriodicalId":305,"journal":{"name":"Electrochimica Acta","volume":null,"pages":null},"PeriodicalIF":5.5000,"publicationDate":"2024-09-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Electrochimica Acta","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0013468624013355","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"ELECTROCHEMISTRY","Score":null,"Total":0}
引用次数: 0
Abstract
The microemulsion (water-in-oil) method is used to prepare novel silver catalysts onto three different carbon supports (multi-walled carbon nanotubes (MWCNT), mesoporous carbon (MC) and Vulcan carbon (C)). It allows to control the Ag particle growth and produces particles that range between 2 and 3 nm. The Ag-based catalysts are characterised by scanning transmission electron microscopy (STEM) with energy-dispersive X-ray spectroscopy (EDS). The electrocatalytic activity towards the oxygen reduction reaction (ORR) in 0.1 M KOH is studied using the rotating disc electrode method. High-angle annular dark-field (HAADF) STEM images reveal the Ag particle size range between 1.8 and 2.4 nm, and the EDS mapping shows uniform Ag distribution on the substrates used. Ag1/MC (two-step synthesis) and Ag2/MC (one-step synthesis) catalysts prepared onto the MC support show the highest mass activity of 30–37 A g−1. The two-step synthesis method is preferred to prepare Ag/MWCNT and Ag/C catalysts. The mass activity of the Ag1/MWCNT catalyst is more than two times higher than that of Ag2/MWCNT. Ag1/MWCNT shows the highest electrochemical stability after the accelerated durability test, with only a 6 mV shift in half-wave potential. The microemulsion method is very promising for the production of highly stable Ag-based catalysts with Ag particles smaller than 3 nm in size.
期刊介绍:
Electrochimica Acta is an international journal. It is intended for the publication of both original work and reviews in the field of electrochemistry. Electrochemistry should be interpreted to mean any of the research fields covered by the Divisions of the International Society of Electrochemistry listed below, as well as emerging scientific domains covered by ISE New Topics Committee.