{"title":"Organic–Inorganic Copolymerization Induced Oriented Crystallization for Robust Lightweight Porous Composite","authors":"Xin Yu, Kangren Kong, Xiaoming Ma, Yadong Yu, Yinlin Shen, Yanhua Sang, Jie Wang, Sudan Shen, Xurong Xu, Zhaoming Liu, Ruikang Tang","doi":"10.1002/smll.202403443","DOIUrl":null,"url":null,"abstract":"<p>Porous composites are important in engineering fields for their lightweight, thermal insulation, and mechanical properties. However, increased porosity commonly decreases the robustness, making a trade-off between mechanics and weight. Optimizing the strength of solid structure is a promising way to co-enhance the robustness and lightweight properties. Here, acrylamide and calcium phosphate ionic oligomers are copolymerized, revealing a pre-interaction of these precursors induced oriented crystallization of inorganic nanostructures during the linear polymerization of acrylamide, leading to the spontaneous formation of a bone-like nanostructure. The resulting solid phase shows enhanced mechanics, surpassing most biological materials. The bone-like nanostructure remains intact despite the introduction of porous structures at higher levels, resulting in a porous composite (P-APC) with high strength (yield strength of 10.5 MPa) and lightweight properties (density below 0.22 g cm<sup>−3</sup>). Notably, the density-strength property surpasses most reported porous materials. Additionally, P-APC shows ultralow thermal conductivity (45 mW m<sup>−1</sup> k<sup>−1</sup>) due to its porous structure, making its strength and thermal insulation superior to many reported materials. This work provides a robust, lightweight, and thermal insulating composite for practical application. It emphasizes the advantage of prefunctionalization of ionic oligomers for organic–inorganic copolymerization in creating oriented nanostructure with toughened mechanics, offering an alternative strategy to produce robust lightweight materials.</p>","PeriodicalId":228,"journal":{"name":"Small","volume":"20 48","pages":""},"PeriodicalIF":13.0000,"publicationDate":"2024-09-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Small","FirstCategoryId":"88","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/smll.202403443","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
Porous composites are important in engineering fields for their lightweight, thermal insulation, and mechanical properties. However, increased porosity commonly decreases the robustness, making a trade-off between mechanics and weight. Optimizing the strength of solid structure is a promising way to co-enhance the robustness and lightweight properties. Here, acrylamide and calcium phosphate ionic oligomers are copolymerized, revealing a pre-interaction of these precursors induced oriented crystallization of inorganic nanostructures during the linear polymerization of acrylamide, leading to the spontaneous formation of a bone-like nanostructure. The resulting solid phase shows enhanced mechanics, surpassing most biological materials. The bone-like nanostructure remains intact despite the introduction of porous structures at higher levels, resulting in a porous composite (P-APC) with high strength (yield strength of 10.5 MPa) and lightweight properties (density below 0.22 g cm−3). Notably, the density-strength property surpasses most reported porous materials. Additionally, P-APC shows ultralow thermal conductivity (45 mW m−1 k−1) due to its porous structure, making its strength and thermal insulation superior to many reported materials. This work provides a robust, lightweight, and thermal insulating composite for practical application. It emphasizes the advantage of prefunctionalization of ionic oligomers for organic–inorganic copolymerization in creating oriented nanostructure with toughened mechanics, offering an alternative strategy to produce robust lightweight materials.
期刊介绍:
Small serves as an exceptional platform for both experimental and theoretical studies in fundamental and applied interdisciplinary research at the nano- and microscale. The journal offers a compelling mix of peer-reviewed Research Articles, Reviews, Perspectives, and Comments.
With a remarkable 2022 Journal Impact Factor of 13.3 (Journal Citation Reports from Clarivate Analytics, 2023), Small remains among the top multidisciplinary journals, covering a wide range of topics at the interface of materials science, chemistry, physics, engineering, medicine, and biology.
Small's readership includes biochemists, biologists, biomedical scientists, chemists, engineers, information technologists, materials scientists, physicists, and theoreticians alike.