Mauro R.S. Silveira , Vicente F. Moritz , Carlos A. Ferreira , Laurent Ferry , José-Marie Lopez-Cuesta
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引用次数: 0
Abstract
The modification of Novolac epoxy with the organophosphorus compound 9,10-dihydro-9-oxa-10-phosphaphenanthren-10-oxide (DOPO) to reduce flammability and its influence on curing reactions has been investigated. Three aromatic diamine curing agents were used, namely 4,4′-diaminodiphenylmethane (DDM), 4,4′-diaminodiphenylsulphone (DDS), and diethyltoluenediamine (DETDA). The thermal stability and dynamic-mechanical behaviour of the cured resin depend on interactions of the curing agent with DOPO. The onset degradation temperature decreased with increasing phosphorus content, indicating the influence of DOPO on thermal stability. The DDM 3 %P sample exhibited the highest glass transition (Tg) of 136 °C, while DDS-crosslinked simples displayed the highest Tg of 147 °C among all samples. An improvement in the reaction of Novolac epoxy to fire was achieved by incorporating DOPO compound, as indicated by cone calorimetry results, showing up to a 67 % reduction in the peak heat release rate (pHRR) and 53 % reduction in total heat release (THR) for DDM 3 %P. The modified samples containing DOPO presented a self-extinguishing performance, displaying a UL-94 V-0 rating and a limiting oxygen index (LOI) values reached a maximum of 37.1 % for DDM 3 %P, with less flame propagation than for neat Novolac epoxy.
期刊介绍:
Thermochimica Acta publishes original research contributions covering all aspects of thermoanalytical and calorimetric methods and their application to experimental chemistry, physics, biology and engineering. The journal aims to span the whole range from fundamental research to practical application.
The journal focuses on the research that advances physical and analytical science of thermal phenomena. Therefore, the manuscripts are expected to provide important insights into the thermal phenomena studied or to propose significant improvements of analytical or computational techniques employed in thermal studies. Manuscripts that report the results of routine thermal measurements are not suitable for publication in Thermochimica Acta.
The journal particularly welcomes papers from newly emerging areas as well as from the traditional strength areas:
- New and improved instrumentation and methods
- Thermal properties and behavior of materials
- Kinetics of thermally stimulated processes