{"title":"Enhanced Hydrogen Bonding Through Strong Water-Locking Additives for Long-Term Cycling of Zinc Ion Batteries","authors":"Ruheng Jiang, Tuoya Naren, Yuejiao Chen, Zhao Chen, Chunxiao Zhang, Yiman Xie, Libao Chen, Yuyang Qi, Qingfei Meng, Weifeng Wei, Liangjun Zhou","doi":"10.1002/adfm.202411477","DOIUrl":null,"url":null,"abstract":"The promising energy storage devices, zinc ion batteries (ZIBs), face challenges such as dendritic growth and side reactions, which hinder their application and development. As a polar group, hydroxyl groups can utilize hydrogen bonding to stably anchor water molecules, preventing contact between water and the anode. Moreover, they can attract and guide Zn<sup>2+</sup> to rapidly and uniformly deposit on the anode. Here, the introduction of multi-hydroxyl water-locking additive Lactobionic acid (LA) molecules is proposed into conventional electrolytes. Through an in situ reaction between the highly reactive carboxyl groups on LA molecules and the zinc anode, a stable multi-hydroxyl protective layer is formed on the anode surface, effectively preventing interface corrosion and dendritic growth. As a result, the Zn||Zn symmetric cell with LA exhibits remarkable performance, cycling for 2300 h under 1 mA cm<sup>−2</sup> and 1 mAh cm<sup>−2</sup>. Even under more rigorous conditions of 10 mA cm<sup>−2</sup> and 10 mAh cm<sup>−2</sup>, it maintains over 800 h of cycling durability. Moreover, in the Zn||NH<sub>4</sub>V<sub>4</sub>O<sub>10</sub> full cell configuration, an impressive capacity retention rate of 80.35% after 2000 cycles at a current density of 5 A g<sup>−1</sup>. This innovative method can open a new avenue for designing high-performance ZIBs.","PeriodicalId":112,"journal":{"name":"Advanced Functional Materials","volume":null,"pages":null},"PeriodicalIF":18.5000,"publicationDate":"2024-09-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Advanced Functional Materials","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.1002/adfm.202411477","RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
The promising energy storage devices, zinc ion batteries (ZIBs), face challenges such as dendritic growth and side reactions, which hinder their application and development. As a polar group, hydroxyl groups can utilize hydrogen bonding to stably anchor water molecules, preventing contact between water and the anode. Moreover, they can attract and guide Zn2+ to rapidly and uniformly deposit on the anode. Here, the introduction of multi-hydroxyl water-locking additive Lactobionic acid (LA) molecules is proposed into conventional electrolytes. Through an in situ reaction between the highly reactive carboxyl groups on LA molecules and the zinc anode, a stable multi-hydroxyl protective layer is formed on the anode surface, effectively preventing interface corrosion and dendritic growth. As a result, the Zn||Zn symmetric cell with LA exhibits remarkable performance, cycling for 2300 h under 1 mA cm−2 and 1 mAh cm−2. Even under more rigorous conditions of 10 mA cm−2 and 10 mAh cm−2, it maintains over 800 h of cycling durability. Moreover, in the Zn||NH4V4O10 full cell configuration, an impressive capacity retention rate of 80.35% after 2000 cycles at a current density of 5 A g−1. This innovative method can open a new avenue for designing high-performance ZIBs.
期刊介绍:
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