Ruifeng Han, Tao Jiang, Zhiqiao Wang, Rongrong Xue, Xinhao Liu, Yinwen Tang, Zhenhui Qi, Yue Ma
{"title":"Reconfiguring Zn2+ Solvation Network and Interfacial Chemistry of Zn Metal Anode with Molecular Engineered Crown Ether Additive","authors":"Ruifeng Han, Tao Jiang, Zhiqiao Wang, Rongrong Xue, Xinhao Liu, Yinwen Tang, Zhenhui Qi, Yue Ma","doi":"10.1002/adfm.202412255","DOIUrl":null,"url":null,"abstract":"The practical deployment of rechargeable aqueous zinc‐ion batteries (RAZBs) in the scaled power system suffers from unregulated Zn dendrite growth as well as parasitic reactions at the zinc foil/aqueous electrolyte interface, leading to insufficient zinc utilization and severe electrode corrosion. Herein, a novel crown ether additive is developed, with tailored molecular engineering, to stepwise regulate the Zn<jats:sup>2+</jats:sup> solvation network and interfacial chemistry of Zn metal anode. The designed crown ether (C5SeCN), featuring zincophilic cyano group and hydrophobic selenium, efficiently reconstructs the solvation sheath of Zn ions at the 0.3 wt.% dose amount. Additionally, the ozone plasma treatment tethers the O<jats:sup>2‐</jats:sup> groups onto the thin‐layer zinc foil, which thus binds Se atoms of the C5SeCN to the Zn anode. The Zn||Zn symmetric cells exhibit a lifespan of over 4500 h at 1 mA cm<jats:sup>−2</jats:sup> and high current density endurance of up to 10 mA cm<jats:sup>−2</jats:sup>. Moreover, the 2 mAh cm<jats:sup>−2</jats:sup> Zn||V<jats:sub>2</jats:sub>O<jats:sub>5</jats:sub> full cell model, at the low N/P ratio of 2.8 with a lean electrolyte (E/C ratio = 10 µL mAh<jats:sup>−1</jats:sup>), enables robust cycling endurance at 2 A g⁻¹ for 300 cycles. This study unravels the interfacial design rationales for maximizing zinc utilization and highlights the commercial potential of crown ether additives for RAZBs development.","PeriodicalId":112,"journal":{"name":"Advanced Functional Materials","volume":null,"pages":null},"PeriodicalIF":18.5000,"publicationDate":"2024-09-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Advanced Functional Materials","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.1002/adfm.202412255","RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
The practical deployment of rechargeable aqueous zinc‐ion batteries (RAZBs) in the scaled power system suffers from unregulated Zn dendrite growth as well as parasitic reactions at the zinc foil/aqueous electrolyte interface, leading to insufficient zinc utilization and severe electrode corrosion. Herein, a novel crown ether additive is developed, with tailored molecular engineering, to stepwise regulate the Zn2+ solvation network and interfacial chemistry of Zn metal anode. The designed crown ether (C5SeCN), featuring zincophilic cyano group and hydrophobic selenium, efficiently reconstructs the solvation sheath of Zn ions at the 0.3 wt.% dose amount. Additionally, the ozone plasma treatment tethers the O2‐ groups onto the thin‐layer zinc foil, which thus binds Se atoms of the C5SeCN to the Zn anode. The Zn||Zn symmetric cells exhibit a lifespan of over 4500 h at 1 mA cm−2 and high current density endurance of up to 10 mA cm−2. Moreover, the 2 mAh cm−2 Zn||V2O5 full cell model, at the low N/P ratio of 2.8 with a lean electrolyte (E/C ratio = 10 µL mAh−1), enables robust cycling endurance at 2 A g⁻¹ for 300 cycles. This study unravels the interfacial design rationales for maximizing zinc utilization and highlights the commercial potential of crown ether additives for RAZBs development.
期刊介绍:
Firmly established as a top-tier materials science journal, Advanced Functional Materials reports breakthrough research in all aspects of materials science, including nanotechnology, chemistry, physics, and biology every week.
Advanced Functional Materials is known for its rapid and fair peer review, quality content, and high impact, making it the first choice of the international materials science community.