A dual resin application system for improved bamboo-wood bonding

IF 3.2 3区 材料科学 Q2 ENGINEERING, CHEMICAL
Jialin Zhang , Kate Semple , Meiling Chen , Chunping Dai
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Abstract

In this work, a dual resin application system using commercial phenol formaldehyde (PF) resins with different molecular weight (MW) was investigated to improve bonding performance of bamboo and wood composite laminates. Water droplet contact angle was deemed to be unreliable for assessing resin wettability on bamboo due to its unique tissue structure compared with wood. Microscopic observation of the resin penetration showed high MW PF largely remained in the glueline and only entered the lumens of cut or damaged bamboo cells near the bondline. Low MW PF appeared in cell corners of bamboo parenchyma but not lumens. Applying low MW PF to the bamboo and high MW PF to the wood surface separately significantly improved bond shear strength with reduced difference between dry and wet conditions. The dry and wet bond strengths using the new method were enhanced by 36.5 % and 97.4 %, respectively, compared to high MW PF alone. The results suggest that low MW PF can permeate bamboo cell walls and fortify them against swelling and stress on the bamboo-resin interface in wet conditions. Further modifications are required to produce a stronger adhesive than the bamboo tissue to improve wet shear fiber failure rates and develop a viable structural bond qualification test for bamboo and bamboo-wood composites.

改进竹木粘合的双树脂应用系统
在这项工作中,研究了使用不同分子量(MW)的商用苯酚甲醛(PF)树脂的双树脂应用系统,以改善竹木复合层压板的粘合性能。与木材相比,竹子具有独特的组织结构,因此水滴接触角被认为无法用于评估树脂在竹子上的润湿性。对树脂渗透性的显微观察显示,高分子量的全氟辛基磺酰氟大部分停留在胶线上,只有在靠近粘合线的地方才会进入被切割或损坏的竹细胞的腔内。低粘度聚对苯二甲酸出现在竹子实质细胞的角落,但没有进入细胞腔。分别在竹材和木材表面涂抹低粘度聚苯乙烯和高粘度聚苯乙烯可显著提高粘接剪切强度,减少干湿条件下的差异。与单独使用高分子量聚对苯二甲酸乙二醇相比,使用新方法的干、湿粘结强度分别提高了 36.5% 和 97.4%。结果表明,低粘度聚对苯二甲酸乙二醇能渗透竹细胞壁,并在潮湿条件下增强竹细胞壁的抗膨胀性和竹-树脂界面的应力。还需要进一步改进,以生产出比竹子组织更强的粘合剂,从而提高湿剪切纤维的破坏率,并为竹子和竹木复合材料开发出一种可行的结构粘合鉴定测试方法。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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来源期刊
International Journal of Adhesion and Adhesives
International Journal of Adhesion and Adhesives 工程技术-材料科学:综合
CiteScore
6.90
自引率
8.80%
发文量
200
审稿时长
8.3 months
期刊介绍: The International Journal of Adhesion and Adhesives draws together the many aspects of the science and technology of adhesive materials, from fundamental research and development work to industrial applications. Subject areas covered include: interfacial interactions, surface chemistry, methods of testing, accumulation of test data on physical and mechanical properties, environmental effects, new adhesive materials, sealants, design of bonded joints, and manufacturing technology.
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