Highly dispersed g-C3N4 on one-dimensional W18O49/carbon nanofibers for constructing well-connected S-scheme heterojunctions with synchronous H2 evolution and pollutant degradation performance
Ting Yan , Ran Tao , Yanxin Wang , Tongtong Li , Zhenming Chu , Xiaoxing Fan , Kuiyong Liu
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引用次数: 0
Abstract
Synchronous dual-functional photocatalytic reaction can simultaneously consume photogenerated electrons and holes, leading to redox reaction, which is a promising photocatalytic reaction system model. However, the severe recombination of photogenerated charge carriers in photocatalysts limits their photocatalytic performance. In this work, W18O49/C@g-C3N4 S-scheme heterojunctions nanofibers with core-shell structure were prepared through electrospinning combined with the vapor deposition method, for high-performance synchronous photocatalytic H2 evolution and pollutant degradation. The X-ray photoelectron spectroscopy and Mott-Schottky results demonstrated that the S-scheme heterojunctions effectively separate charges while maintaining high redox capacity. The UV-vis-NIR absorption spectra results revealed the LSPR effect in W18O49, which can generate “hot electrons”. The scanning electron microscope images showed that the unique core-shell structure independently consumes electrons and holes, thereby enhancing charge separation and accelerating carrier kinetics. Specifically, the synchronous H2 evolution and RhB degradation efficiency of W18O49/C@g-C3N4 nanofibers were approximately 5.60 and 3.51 times higher than that of W18O49/C, and 2.45 and 22.55 times higher than that of C@g-C3N4 nanofibers, respectively. Furthermore, the ultra-long one-dimensional network structure of W18O49/C@g-C3N4 nanofibers enables easy recycling after liquid reactions. This study presents a novel approach for customizing band structures and unique surface morphology to improve synchronous dual-functional photocatalytic activity.
期刊介绍:
The aim of the journal is to provide a respectful outlet for ''sound science'' papers in all research areas on surfaces and interfaces. We define sound science papers as papers that describe new and well-executed research, but that do not necessarily provide brand new insights or are merely a description of research results.
Surfaces and Interfaces publishes research papers in all fields of surface science which may not always find the right home on first submission to our Elsevier sister journals (Applied Surface, Surface and Coatings Technology, Thin Solid Films)