Elizabeth Chingangbam, Ranjoy Wangkhem, N. Shanta Singh, N. Yaiphaba
{"title":"Blue to Red Emission Tunable Bi3+ co-doped YPO4:Eu3+: Host Emission and Phase Change","authors":"Elizabeth Chingangbam, Ranjoy Wangkhem, N. Shanta Singh, N. Yaiphaba","doi":"10.1007/s10895-024-03926-z","DOIUrl":null,"url":null,"abstract":"<p>Bi<sup>3+</sup>(0, 1, 3, 5, 7, 10, 12 and 15 at.%) co-doped YPO<sub>4</sub>:Eu<sup>3+</sup> have been hydrothermally synthesized. Bi<sup>3+</sup> (<i>x</i> ≥ 1 at.%) co-doping in YPO<sub>4</sub>:Eu<sup>3+</sup> renders mixed crystalline phase of tetragonal to hexagonal. Pure tetragonal phase of Bi<sup>3+</sup> co-doped YPO<sub>4</sub>:Eu<sup>3+</sup> could be achieved upon annealing at 900 °C. The luminescence intensity is improved significantly upon annealing at 900 °C. This is due to the reduction of quenching pathways such as water molecules, dangling bonds, etc. The probability of magnetic dipole and electric dipole transitions is observed to be altered. As-prepared samples show near blue emission, while 900 °C annealed samples exhibit red emission, which could be a potential candidate for display, sensing and biological labelling, etc.</p>","PeriodicalId":15800,"journal":{"name":"Journal of Fluorescence","volume":null,"pages":null},"PeriodicalIF":2.6000,"publicationDate":"2024-09-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Fluorescence","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1007/s10895-024-03926-z","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"BIOCHEMICAL RESEARCH METHODS","Score":null,"Total":0}
引用次数: 0
Abstract
Bi3+(0, 1, 3, 5, 7, 10, 12 and 15 at.%) co-doped YPO4:Eu3+ have been hydrothermally synthesized. Bi3+ (x ≥ 1 at.%) co-doping in YPO4:Eu3+ renders mixed crystalline phase of tetragonal to hexagonal. Pure tetragonal phase of Bi3+ co-doped YPO4:Eu3+ could be achieved upon annealing at 900 °C. The luminescence intensity is improved significantly upon annealing at 900 °C. This is due to the reduction of quenching pathways such as water molecules, dangling bonds, etc. The probability of magnetic dipole and electric dipole transitions is observed to be altered. As-prepared samples show near blue emission, while 900 °C annealed samples exhibit red emission, which could be a potential candidate for display, sensing and biological labelling, etc.
期刊介绍：
Journal of Fluorescence is an international forum for the publication of peer-reviewed original articles that advance the practice of this established spectroscopic technique. Topics covered include advances in theory/and or data analysis, studies of the photophysics of aromatic molecules, solvent, and environmental effects, development of stationary or time-resolved measurements, advances in fluorescence microscopy, imaging, photobleaching/recovery measurements, and/or phosphorescence for studies of cell biology, chemical biology and the advanced uses of fluorescence in flow cytometry/analysis, immunology, high throughput screening/drug discovery, DNA sequencing/arrays, genomics and proteomics. Typical applications might include studies of macromolecular dynamics and conformation, intracellular chemistry, and gene expression. The journal also publishes papers that describe the synthesis and characterization of new fluorophores, particularly those displaying unique sensitivities and/or optical properties. In addition to original articles, the Journal also publishes reviews, rapid communications, short communications, letters to the editor, topical news articles, and technical and design notes.
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