Baoshan Wang, Peiyu Zhao, Xiaona Zhang, Yang Zhang, Yingming Liu
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引用次数: 0
Abstract
Traditional Fenton oxidation is an effective method for reducing pollutants that are difficult to degrade. Owing to the large amounts of Fe(II), acids, and alkalis added in the reaction, large amounts of Fenton sludge are produced, increasing treatment costs and restricting the method’s application. In this study, we developed a three-dimensional electro-Fenton system by adding iron-carbon filler and investigated the effects of different electrolytic cell structure arrangements, particle electrode dosages, sponge iron (SI) to granular activated carbon (GAC) dosage ratios, current densities, H2O2 dosages, and cathodic aeration on nitrobenzene (NB) wastewater treatment. The optimal system conditions were a particle electrode dosage of 100 g/L, SI:GAC mass ratio of 3:1, current density of 30 mA/cm2, H2O2 dosage of 50 mmol/L, cathodic aeration of 0.8 L/min, and hydraulic retention time of 120 min. The average NB removal rate and chemical oxygen demand reached 67.38%±1.05% and 70.60%±1.15%, respectively, for which the increase in Fenton sludge was 891.8 mg/L. Different from the traditional Fenton process, additional Fe(II) was not required in the process used herein, reducing iron sludge accumulation and lowering the operating costs of using Fenton sludge as a hazardous waste treatment. In addition, the process applied in this study was able to reduce the chemical amounts used and increase the treatment efficiency. The reductions in sludge treatment costs and secondary pollutants make the proposed process an efficient and sustainable alternative for treating NB wastewater.
期刊介绍:
Frontiers of Environmental Science & Engineering (FESE) is an international journal for researchers interested in a wide range of environmental disciplines. The journal''s aim is to advance and disseminate knowledge in all main branches of environmental science & engineering. The journal emphasizes papers in developing fields, as well as papers showing the interaction between environmental disciplines and other disciplines.
FESE is a bi-monthly journal. Its peer-reviewed contents consist of a broad blend of reviews, research papers, policy analyses, short communications, and opinions. Nonscheduled “special issue” and "hot topic", including a review article followed by a couple of related research articles, are organized to publish novel contributions and breaking results on all aspects of environmental field.