Xue Hua Wang, Mei Ju Luo, Xinyu Li, Qingling Yang, Zhishun Guo, Hao Lin Zou, Hong Qun Luo, Nian Bing Li, Bang Lin Li
{"title":"A Hydrogel-Based Sustained Release System for the Recyclable Uses of Formaldehyde Monitoring in Foods","authors":"Xue Hua Wang, Mei Ju Luo, Xinyu Li, Qingling Yang, Zhishun Guo, Hao Lin Zou, Hong Qun Luo, Nian Bing Li, Bang Lin Li","doi":"10.1039/d4ay01155d","DOIUrl":null,"url":null,"abstract":"4-amino-3-hydramidin-5-mercapto-1, 2, 4-triazacene (AHMT) is pre-doped into agarose hydrogels, and consequently, sustained hydrogel systems with the modulated release performance are constructed, contributing to the point-of-care detections of formaldehyde (FA) with characteristics of simple operation and recyclable uses. With the increases of FA concentrations, the absorbance of those upper-layer solutions responses with linear relationships and the reaction colors gradually increase. The detection of limit is calculated to be 0.013 μg mL-1. In order to verify the practical application, a simple, rapid and low-cost FA detection platform is built on the basis of condition optimizations, and the method has merits of comparable simplicity, high sensitivity and selectivity. More importantly, the developed hydrogels route is recyclable and can be used at least five times without any loss of comparable sensing performance. Significantly, the sensory hydrogels can be employed by the non-skilled people for monitoring food safety of samples, and applied for the practical detection of FA in foods.","PeriodicalId":64,"journal":{"name":"Analytical Methods","volume":null,"pages":null},"PeriodicalIF":2.7000,"publicationDate":"2024-09-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Analytical Methods","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1039/d4ay01155d","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, ANALYTICAL","Score":null,"Total":0}
引用次数: 0
Abstract
4-amino-3-hydramidin-5-mercapto-1, 2, 4-triazacene (AHMT) is pre-doped into agarose hydrogels, and consequently, sustained hydrogel systems with the modulated release performance are constructed, contributing to the point-of-care detections of formaldehyde (FA) with characteristics of simple operation and recyclable uses. With the increases of FA concentrations, the absorbance of those upper-layer solutions responses with linear relationships and the reaction colors gradually increase. The detection of limit is calculated to be 0.013 μg mL-1. In order to verify the practical application, a simple, rapid and low-cost FA detection platform is built on the basis of condition optimizations, and the method has merits of comparable simplicity, high sensitivity and selectivity. More importantly, the developed hydrogels route is recyclable and can be used at least five times without any loss of comparable sensing performance. Significantly, the sensory hydrogels can be employed by the non-skilled people for monitoring food safety of samples, and applied for the practical detection of FA in foods.
将 4-amino-3-hydramidin-5-mercapto-1, 2, 4-triazacene (AHMT) 预先掺杂到琼脂糖水凝胶中,从而构建了具有调节释放性能的持续水凝胶系统,有助于实现操作简单、可回收利用的甲醛(FA)床旁检测。随着 FA 浓度的增加,上层溶液的吸光度呈线性关系,反应颜色逐渐加深。经计算,其检测限为 0.013 μg mL-1。为了验证该方法的实际应用价值,在条件优化的基础上,建立了一个简单、快速、低成本的 FA 检测平台,该方法具有操作简便、灵敏度高、选择性强等优点。更重要的是,所开发的水凝胶路线是可回收的,至少可以使用五次,而不会损失相当的传感性能。值得注意的是,非专业人员也可以使用这种传感水凝胶来监测样品的食品安全,并将其应用于食品中 FA 的实际检测。