Sulfonated carbon–based heterogeneous acid catalysts in direct biomass redox flow fuel cell: A review

IF 1.8 4区 工程技术 Q3 Chemical Engineering
Boniface Ifeanyi Ugwu, Christogonus Oduney Akalezi, Innocent Sunday Ike, Toochukwu Eqwutosi Ogbulie, Emeka Emmanuel Oguzie
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Abstract

This review focused on the potential applications of sulfonated carbon–based heterogeneous acid catalysts for the hydrolysis of lignocellulosic biomass (LCB) fuel feedstock and the development of membrane electrode assembly (MEA) for the direct biomass redox flow fuel cell (DBRFFC). LCBs are hydrolysed to yield simple sugars, which are subsequently oxidized over catalysts in the anode tank of the DBRFFC to generate electricity. Ferric chloride used as a catalyst in the DBRFFC is not efficient for glucose production from LCB, such that the power performance of the DBRFFC is affected during glucose oxidation due to low glucose yield from LCB for electron generation. Sulfonated carbon–based solid acid catalysts (SCSACs) have been established as efficient catalysts for the hydrolysis of LCB and as metal catalyst supports for the fabrication of MEA for further oxidation of glucose and its oxidation by‐products. These capabilities of SCSACs can be explored and applied to significantly improve the power output of the DBRFFC through efficient hybrid catalyst design. There is still a scarcity of literature on this subject and their combination with ferric chloride to enhance glucose yield and oxidation in DBRFFC. This gap was filled by discussing the various types of sulfonated carbon–based catalysts, highlighting their synthesis routes, and their applications in organic compound synthesis, and membrane electrode development in DBRFFC. The knowledge derived will certainly be beneficial to researchers willing to improve the performance of DBRFFC through molecular catalyst design and electrode membrane development for application in DBRFFC.
直接生物质氧化还原流燃料电池中的磺化碳基异质酸催化剂:综述
本综述侧重于磺化碳基异构酸催化剂在水解木质纤维素生物质(LCB)燃料原料中的潜在应用,以及直接生物质氧化还原流燃料电池(DBRFFC)膜电极组件(MEA)的开发。低碳生物质经水解后产生单糖,然后在 DBRFFC 阳极槽中的催化剂作用下氧化发电。DBRFFC 中用作催化剂的氯化铁不能有效地从枸橼酸单质中产生葡萄糖,因此在葡萄糖氧化过程中,由于枸橼酸单质中产生电子的葡萄糖产量低,DBRFFC 的发电性能会受到影响。磺化碳基固体酸催化剂(SCSACs)已被确定为用于水解 LCB 的高效催化剂,以及用于制造 MEA 的金属催化剂载体,以进一步氧化葡萄糖及其氧化副产物。我们可以探索并应用 SCSACs 的这些功能,通过高效的混合催化剂设计来显著提高 DBRFFC 的功率输出。关于这一主题以及将 SCSACs 与氯化铁结合以提高 DBRFFC 中的葡萄糖产量和氧化能力的文献仍然很少。通过讨论各种类型的磺化碳基催化剂,重点介绍它们的合成路线,以及它们在有机化合物合成和 DBRFFC 膜电极开发中的应用,填补了这一空白。所获得的知识必将有益于愿意通过分子催化剂设计和电极膜开发来提高 DBRFFC 性能的研究人员。
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来源期刊
Asia-Pacific Journal of Chemical Engineering
Asia-Pacific Journal of Chemical Engineering 工程技术-工程:化工
CiteScore
3.50
自引率
11.10%
发文量
111
审稿时长
2.8 months
期刊介绍: Asia-Pacific Journal of Chemical Engineering is aimed at capturing current developments and initiatives in chemical engineering related and specialised areas. Publishing six issues each year, the journal showcases innovative technological developments, providing an opportunity for technology transfer and collaboration. Asia-Pacific Journal of Chemical Engineering will focus particular attention on the key areas of: Process Application (separation, polymer, catalysis, nanotechnology, electrochemistry, nuclear technology); Energy and Environmental Technology (materials for energy storage and conversion, coal gasification, gas liquefaction, air pollution control, water treatment, waste utilization and management, nuclear waste remediation); and Biochemical Engineering (including targeted drug delivery applications).
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