Effect of silane coupling agent on mechanical properties, flame retardancy, and ceramifiable behavior of ceramifiable flame-retardant silicone rubber composite

Abstract

In order to improve the dispersibility of inorganic fillers and enhance its ceramifiable flame-retardant efficiency, the ceramifiable flame-retardant silicone rubber composites were prepared using glass powder, zinc borate, ammonium polyphosphate, mica powder, platinum catalyst as ceramifiable flame-retardant agent, and various silane coupling agents as interfacial modifier. The micromorphology, mechanical properties, flame retardancy, thermal stability, and combustion behavior of ceramifiable flame-retardant silicone rubber composites, as well as the flexural strength of the corresponding ceramics generated after pyrolysis of the composites were examined. The results reveal that the inclusion of silane coupling agents improves the dispersibility of ceramifiable flame-retardant agents substantially. The mechanical properties, flame retardancy, thermal stability, and combustion behavior of ceramifiable flame-retardant silicone rubber composites are all improved. When compared to a composite without a silane coupling agent, the tensile strength of the composite can be improved by up to 1.9 times. Only 0.5phr silane coupling agent is required to raise the vertical combustion rating from V-1 to V-0, and the composite with 3 phr KH570 has a LOI value of 38.6. Meanwhile, the heat release rate of the composite is reduced to a certain extent, and the time to ignition and residue are dramatically enhanced after the addition of silane coupling agent in the cone calorimetry test. Moreover, flexural strength of the corresponding ceramics generated after pyrolysis of the composites rapidly increases with increasing silane coupling agent content, which can reach to 24.7 MPa with addition of 3 phr KH570.