Chemosensory Properties of Nanocomposite Ti0.2V1.8CTx–V2O5–SnO2

IF 1.8 3区 化学 Q3 CHEMISTRY, INORGANIC & NUCLEAR
E. P. Simonenko, A. S. Mokrushin, I. A. Nagornov, Yu. M. Gorban, T. L. Simonenko, N. P. Simonenko, N. T. Kuznetsov
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引用次数: 0

Abstract

The method of modification of accordion-like complex Ti0.2V1.8CTx MXene with tin(IV) and vanadium oxides was developed based on hydrothermal synthesis of SnO2 in water-alcoholic medium in the presence of dispersed particles of two-dimensional vanadium-titanium carbide. Coating Ti0.2V1.8CTx-10 mol % SnO2 was deposited by microplotter printing on a specialized substrate followed by heat treatment in air at 300°С for 1 h. For the formed nanocomposite layer Ti0.2V1.8CTx–V2O5–SnO2, chemosensor properties were comprehensively studied for a number of analyte gases, including 100 ppm CO, NH3, NO2, benzene, acetone, ethanol, 1000 ppm H2, methane, and 10% oxygen. High sensitivity and selectivity of the nanocomposite at operating temperatures of 150 and 200°С to nitrogen dioxide were shown, the responses to 100 ppm NO2 were found to be 281 and 873%, respectively.

Abstract Image

纳米复合材料 Ti0.2V1.8CTx-V2O5-SnO2 的化学感应特性
摘要 开发了用锡(IV)和钒氧化物改性手风琴状络合物 Ti0.2V1.8CTx MXene 的方法,其基础是在二维碳化钒钛分散颗粒存在下,在水-醇介质中水热合成 SnO2。对于形成的纳米复合层 Ti0.2V1.8CTx-V2O5-SnO2,对多种分析气体(包括 100 ppm CO、NH3、NO2、苯、丙酮、乙醇、1000 ppm H2、甲烷和 10% 氧气)的化学传感器性能进行了全面研究。结果表明,在 150 和 200°С 的工作温度下,纳米复合材料对二氧化氮具有高灵敏度和高选择性,对 100 ppm 二氧化氮的响应分别为 281% 和 873%。
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来源期刊
Russian Journal of Inorganic Chemistry
Russian Journal of Inorganic Chemistry 化学-无机化学与核化学
CiteScore
3.10
自引率
38.10%
发文量
237
审稿时长
3 months
期刊介绍: Russian Journal of Inorganic Chemistry is a monthly periodical that covers the following topics of research: the synthesis and properties of inorganic compounds, coordination compounds, physicochemical analysis of inorganic systems, theoretical inorganic chemistry, physical methods of investigation, chemistry of solutions, inorganic materials, and nanomaterials.
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