A. O. Borodin, E. Yu. Filatov, P. E. Plusnin, N. V. Kuratieva, S. V. Korenev, G. A. Kostin
{"title":"New Double Complex Salts [M(im)n][RuNOCl5] (M = Ni, Cu): Synthesis, Structure, and Thermal Properties","authors":"A. O. Borodin, E. Yu. Filatov, P. E. Plusnin, N. V. Kuratieva, S. V. Korenev, G. A. Kostin","doi":"10.1134/s003602362470058x","DOIUrl":null,"url":null,"abstract":"<h3 data-test=\"abstract-sub-heading\">Abstract</h3><p>Procedures for the synthesis of new double complex salts [Cu(im)<sub>4</sub>][RuNOCl<sub>5</sub>], [Ni(im)<sub>6</sub>][RuNOCl<sub>5</sub>]·H<sub>2</sub>O, and <i>p</i>-[Ni(im)<sub>4</sub>(DMF)<sub>2</sub>][RuNOCl<sub>5</sub>] have been developed and their crystal structure have been determined. Thermal properties of the synthesized DCS have been studied under inert and reducing atmospheres using synchronous TG–DTA and ex situ XRD of intermediate and final thermolysis products. It has been found that thermal decomposition occurs in three stages. Thermolysis of [Cu(im)<sub>4</sub>][RuNOCl<sub>5</sub>] under inert and reducing atmospheres gives rise to the mixture of copper and ruthenium, while the thermal decomposition of [Ni(im)<sub>6</sub>][RuNOCl<sub>5</sub>]·H<sub>2</sub>O under an inert atmosphere results in a mixture of nickel and ruthenium. A supersaturated Ni<sub>0.27</sub>Ru<sub>0.73</sub> solid solution can be obtained in the nickel-ruthenium system upon thermolysis under a reducing atmosphere at temperature up to 400°C. Increase in thermolysis temperature up to 800°C leads to the partial decomposition of the solid solution.</p>","PeriodicalId":762,"journal":{"name":"Russian Journal of Inorganic Chemistry","volume":"6 1","pages":""},"PeriodicalIF":1.8000,"publicationDate":"2024-09-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Russian Journal of Inorganic Chemistry","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1134/s003602362470058x","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
引用次数: 0
Abstract
Procedures for the synthesis of new double complex salts [Cu(im)4][RuNOCl5], [Ni(im)6][RuNOCl5]·H2O, and p-[Ni(im)4(DMF)2][RuNOCl5] have been developed and their crystal structure have been determined. Thermal properties of the synthesized DCS have been studied under inert and reducing atmospheres using synchronous TG–DTA and ex situ XRD of intermediate and final thermolysis products. It has been found that thermal decomposition occurs in three stages. Thermolysis of [Cu(im)4][RuNOCl5] under inert and reducing atmospheres gives rise to the mixture of copper and ruthenium, while the thermal decomposition of [Ni(im)6][RuNOCl5]·H2O under an inert atmosphere results in a mixture of nickel and ruthenium. A supersaturated Ni0.27Ru0.73 solid solution can be obtained in the nickel-ruthenium system upon thermolysis under a reducing atmosphere at temperature up to 400°C. Increase in thermolysis temperature up to 800°C leads to the partial decomposition of the solid solution.
期刊介绍：
Russian Journal of Inorganic Chemistry is a monthly periodical that covers the following topics of research: the synthesis and properties of inorganic compounds, coordination compounds, physicochemical analysis of inorganic systems, theoretical inorganic chemistry, physical methods of investigation, chemistry of solutions, inorganic materials, and nanomaterials.
求助内容：
应助结果提醒方式：
京公网安备 11010802042870号
