Liquid–Liquid Equilibria Data and Thermodynamic Modeling of {Mesityl Oxide + Diethoxymethane + Water} Ternary System at 303.15, 313.15, 323.15 K Under 101.325 kPa

IF 1.4 4区 化学 Q4 CHEMISTRY, PHYSICAL
Hongyue Guo, Tao Li, Qingsong Li, Zhongtao Li
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引用次数: 0

Abstract

The liquid–liquid equilibrium (LLE) of the mesityl oxide + diethoxymethane + water was determined at 303.15, 313.15 and 323.15 K under 101.325 kPa, which was consistent with the Treybal’s type II ternary phase behavior. The distribution coefficients (D) and selectivity coefficients (S) were used to evaluate the extraction ability of mesityl oxide to extract diethoxymethane from water. The experimental data were correlated with the NRTL and UNIQUAC thermodynamic models, and the RMSD values are both less than 0.47%, indicating that the two models can well correlate the experimental data.

Abstract Image

在 303.15、313.15、323.15 K 和 101.325 kPa 下{氧化甲酯 + 二乙氧基甲烷 + 水}三元体系的液液平衡数据和热力学模型
在 303.15、313.15 和 323.15 K(101.325 kPa)条件下测定了氧化甲硅烷+二乙氧基甲烷+水的液液平衡(LLE),结果与 Treybal 的 II 型三元相行为一致。分配系数(D)和选择性系数(S)用于评估氧化甲硅烷从水中萃取二乙氧基甲烷的能力。实验数据与 NRTL 和 UNIQUAC 热力学模型进行了相关性分析,其 RMSD 值均小于 0.47%,表明这两个模型能够很好地对实验数据进行相关性分析。
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来源期刊
Journal of Solution Chemistry
Journal of Solution Chemistry 化学-物理化学
CiteScore
2.30
自引率
0.00%
发文量
87
审稿时长
3-8 weeks
期刊介绍: Journal of Solution Chemistry offers a forum for research on the physical chemistry of liquid solutions in such fields as physical chemistry, chemical physics, molecular biology, statistical mechanics, biochemistry, and biophysics. The emphasis is on papers in which the solvent plays a dominant rather than incidental role. Featured topics include experimental investigations of the dielectric, spectroscopic, thermodynamic, transport, or relaxation properties of both electrolytes and nonelectrolytes in liquid solutions.
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