Competitive Li-ion Coordination Constructing Three-Dimensional Transport Network for Ultra-High Ionic Conductivity of Composite Solid-State Electrolyte
Yiteng Ma, Yong Qiu, Ke Yang, Shun Lv, Yuhang Li, Xufei An, Guanyou Xiao, Zhuo Han, Yuetao Ma, Likun Chen, Danfeng Zhang, Wei Lv, Yun Tian, Tingzheng Hou, Ming Liu, Zhen Zhou, Feiyu Kang, Yanbing He
{"title":"Competitive Li-ion Coordination Constructing Three-Dimensional Transport Network for Ultra-High Ionic Conductivity of Composite Solid-State Electrolyte","authors":"Yiteng Ma, Yong Qiu, Ke Yang, Shun Lv, Yuhang Li, Xufei An, Guanyou Xiao, Zhuo Han, Yuetao Ma, Likun Chen, Danfeng Zhang, Wei Lv, Yun Tian, Tingzheng Hou, Ming Liu, Zhen Zhou, Feiyu Kang, Yanbing He","doi":"10.1039/d4ee03134b","DOIUrl":null,"url":null,"abstract":"The porous structure of poly(vinylidene fluoride) (PVDF)-based polymer electrolytes and their disordered ion transport properties restrict the continuous and highly efficient transport of lithium ion (Li+), which exists as the major challenge to further improve the ionic conductivity. Herein, we construct a compact composite solid-state electrolyte with a three-dimensional continuous Li+ transport network by coupling heat-treated polyacrylonitrile fiber network with interconnected metal organic framework coating layer (h-PAN@MOF). The MOF crystal surface exhibits strong interactions with C=O of N,N-dimethylformamide (DMF), which effectively weakens the Li+-O binding strength of DMF in Li+ solvation structure. Highly efficient Li+ transport channels and networks are constructed to achieve a high ionic conductivity of 1.03×10–3 S cm–1. The MOF-participated Li+ coordination environment prompts the formation of a stable interphase. The h-PAN@MOF network also contributes to a high tensile strength (20.84 MPa) of the compact electrolyte. The Li||LiNi0.8Mn0.1Co0.1O2 full cells with h-PAN@MOF network realize robust cycling for 1000 times at 5C. This work provides a facile strategy of regulating the Li+ coordination state and its spatial distribution in solid-state electrolytes for fast-charging solid-state Li metal batteries.","PeriodicalId":72,"journal":{"name":"Energy & Environmental Science","volume":null,"pages":null},"PeriodicalIF":32.4000,"publicationDate":"2024-09-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Energy & Environmental Science","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.1039/d4ee03134b","RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
The porous structure of poly(vinylidene fluoride) (PVDF)-based polymer electrolytes and their disordered ion transport properties restrict the continuous and highly efficient transport of lithium ion (Li+), which exists as the major challenge to further improve the ionic conductivity. Herein, we construct a compact composite solid-state electrolyte with a three-dimensional continuous Li+ transport network by coupling heat-treated polyacrylonitrile fiber network with interconnected metal organic framework coating layer (h-PAN@MOF). The MOF crystal surface exhibits strong interactions with C=O of N,N-dimethylformamide (DMF), which effectively weakens the Li+-O binding strength of DMF in Li+ solvation structure. Highly efficient Li+ transport channels and networks are constructed to achieve a high ionic conductivity of 1.03×10–3 S cm–1. The MOF-participated Li+ coordination environment prompts the formation of a stable interphase. The h-PAN@MOF network also contributes to a high tensile strength (20.84 MPa) of the compact electrolyte. The Li||LiNi0.8Mn0.1Co0.1O2 full cells with h-PAN@MOF network realize robust cycling for 1000 times at 5C. This work provides a facile strategy of regulating the Li+ coordination state and its spatial distribution in solid-state electrolytes for fast-charging solid-state Li metal batteries.
期刊介绍:
Energy & Environmental Science, a peer-reviewed scientific journal, publishes original research and review articles covering interdisciplinary topics in the (bio)chemical and (bio)physical sciences, as well as chemical engineering disciplines. Published monthly by the Royal Society of Chemistry (RSC), a not-for-profit publisher, Energy & Environmental Science is recognized as a leading journal. It boasts an impressive impact factor of 8.500 as of 2009, ranking 8th among 140 journals in the category "Chemistry, Multidisciplinary," second among 71 journals in "Energy & Fuels," second among 128 journals in "Engineering, Chemical," and first among 181 scientific journals in "Environmental Sciences."
Energy & Environmental Science publishes various types of articles, including Research Papers (original scientific work), Review Articles, Perspectives, and Minireviews (feature review-type articles of broad interest), Communications (original scientific work of an urgent nature), Opinions (personal, often speculative viewpoints or hypotheses on current topics), and Analysis Articles (in-depth examination of energy-related issues).