Dr. Shu Zhang, Liyan Zhang, Aocheng Chen, Yi An, Dr. Xu-Man Chen, Prof. Hong Yang, Prof. Quan Li
{"title":"Innentitelbild: Cucurbit[8]uril-Mediated Supramolecular Heterodimerisation and Photoinduced [2+2] Heterocycloaddition to Generate Unexpected [2]Rotaxanes (Angew. Chem. 39/2024)","authors":"Dr. Shu Zhang, Liyan Zhang, Aocheng Chen, Yi An, Dr. Xu-Man Chen, Prof. Hong Yang, Prof. Quan Li","doi":"10.1002/ange.202413886","DOIUrl":null,"url":null,"abstract":"<p><b>Supramolecular hetero-self-assembly</b> is more challenging and meaningful compared to homo-self-assembly in many areas. In their Research Article (e202410130), Xu-Man Chen, Hong Yang, Quan Li et al. present a cucurbit[8]uril-mediated heterodimerization, which enables the occurrence of a rare cucurbit[8]uril-mediated [2+2] heterocycloaddition under UV irradiation. The final product is found to be an unexpected [2]rotaxane, developing into a novel photochemical template synthesis of mechanically interlocked molecules.\n <figure>\n <div><picture>\n <source></source></picture><p></p>\n </div>\n </figure>\n </p>","PeriodicalId":7803,"journal":{"name":"Angewandte Chemie","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2024-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/ange.202413886","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Angewandte Chemie","FirstCategoryId":"1085","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/ange.202413886","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
Abstract
Supramolecular hetero-self-assembly is more challenging and meaningful compared to homo-self-assembly in many areas. In their Research Article (e202410130), Xu-Man Chen, Hong Yang, Quan Li et al. present a cucurbit[8]uril-mediated heterodimerization, which enables the occurrence of a rare cucurbit[8]uril-mediated [2+2] heterocycloaddition under UV irradiation. The final product is found to be an unexpected [2]rotaxane, developing into a novel photochemical template synthesis of mechanically interlocked molecules.
与同源自组装相比，超分子异源自组装在许多领域更具挑战性和意义。在他们的研究文章（e202410130）中，Xu-Man Chen、Hong Yang、Quan Li 等人提出了一种葫芦[8]脲介导的异源二聚体，在紫外光照射下实现了罕见的葫芦[8]脲介导的[2+2]杂环加成。最终产物是一种意想不到的[2]rotaxane，从而发展成为一种新的机械连锁分子的光化学模板合成方法。
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