Comparative analysis of corrosion resistance and purification performance of geopolymer recycled pervious concrete under acid rain soaking and spraying simulation

IF 4.4 2区 化学 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY
Minqi Hua , Bo Chen , Hui Liu , Pinghua Zhu , Xinjie Wang , Chunhong Chen
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Abstract

Acid rain corrosion is a critical factor contributing to the increased susceptibility of concrete pavements to cracking and reduced service life, raising significant safety concerns. This research aims to investigate the acid rain corrosion resistance and purification performance of geopolymer recycled pervious concrete (GRPC) with top-bottom interconnected channels under acid rain soaking and spraying simulation tests. The impacts of acid rain exposure on the compressive strength, permeability coefficient, mass loss, neutralization depth of GRPC, and the pH value of percolating acid rainwater were analyzed. The results proved that GRPC exhibited excellent resistance to simulated acid rain with a pH of 4.0. Furthermore, employing a combination of sodium hydroxide and sodium silicate as alkali-activators provided the optimal acid rain corrosion resistance. Additionally, in the early stage of acid rain exposure, acid rain was neutralized by the sodium carbonate formed through efflorescence. While in the middle-later stage, the migrating alkaline substances in GRPC matrix directly neutralized the pH of acid rain. Notably, after 28 days of simulated acid rain spraying, GRPC maintained its ability to purify the acid rain flowing through its channels, successfully raising the pH from 4 to a range between 7 and 8, demonstrating an effective acid rain purification capability. In conclusion, GRPC can transform the efflorescence issue in concrete into an effective means to counteract acid rain corrosion, thereby equipping concrete pavements with the dual advantages of alleviating urban waterlogging and resisting acid rain corrosion. This renders GRPC a promising avenue for both academic research and practical engineering applications.

土工聚合物再生透水混凝土在酸雨浸泡和喷淋模拟条件下的抗腐蚀和净化性能对比分析
酸雨腐蚀是导致混凝土路面更易开裂和使用寿命缩短的关键因素,引发了重大的安全问题。本研究旨在研究在酸雨浸泡和喷淋模拟试验下,具有上下互联通道的土工聚合物再生透水混凝土(GRPC)的抗酸雨腐蚀性能和净化性能。分析了酸雨暴露对土工聚合物再生透水混凝土的抗压强度、渗透系数、质量损失、中和深度以及下渗酸雨水pH值的影响。结果表明,GRPC 对 pH 值为 4.0 的模拟酸雨具有出色的耐受性。此外,采用氢氧化钠和硅酸钠组合作为碱活化剂可提供最佳的耐酸雨腐蚀性能。此外,在酸雨暴露的早期阶段,酸雨会被渗出形成的碳酸钠中和。而在中后期,GRPC 基质中迁移的碱性物质直接中和了酸雨的 pH 值。值得注意的是,经过 28 天的模拟酸雨喷洒后,GRPC 仍能保持净化流经其通道的酸雨的能力,成功地将 pH 值从 4 提高到 7 至 8 之间,显示出有效的酸雨净化能力。总之,GRPC 可以将混凝土中的渗出问题转化为抵御酸雨腐蚀的有效手段,从而使混凝土路面具有缓解城市内涝和抵御酸雨腐蚀的双重优势。这使得 GRPC 在学术研究和实际工程应用方面都大有可为。
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来源期刊
CiteScore
7.20
自引率
6.00%
发文量
810
期刊介绍: ACS Applied Polymer Materials is an interdisciplinary journal publishing original research covering all aspects of engineering, chemistry, physics, and biology relevant to applications of polymers. The journal is devoted to reports of new and original experimental and theoretical research of an applied nature that integrates fundamental knowledge in the areas of materials, engineering, physics, bioscience, polymer science and chemistry into important polymer applications. The journal is specifically interested in work that addresses relationships among structure, processing, morphology, chemistry, properties, and function as well as work that provide insights into mechanisms critical to the performance of the polymer for applications.
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