Universal Time and Length Scales of Polar Active Polymer Melts

IF 5.2 Q1 POLYMER SCIENCE
Mattia Alberto Ubertini*, Emanuele Locatelli* and Angelo Rosa*, 
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引用次数: 0

Abstract

We present an in-depth multiscale analysis of the conformations and dynamics of polar active polymers, comparing very dilute and very dense conditions. We unveil characteristic length and time scales, common to both dilute and dense systems, that recapitulate the conformational and dynamical properties of these active polymers upon varying both the polymer size and the strength of the activity. Specifically, we find that a correlation (or looping) length characterizes the polymer conformations and the monomer dynamics. Instead, the dynamics of the center of mass can be fully characterized by the end-to-end mean-square distance and by the associated relaxation time. As such, we show that the dynamics of individual chains in melts of polar active polymers is not controlled by entanglements, but only by the strength of the self-propulsion.

Abstract Image

极性活性聚合物熔体的通用时间和长度尺度
我们对极性活性聚合物的构象和动力学进行了深入的多尺度分析,并对极稀释和极致密条件进行了比较。我们揭示了稀释和致密系统共有的特征长度和时间尺度,这些尺度再现了这些活性聚合物在改变聚合物尺寸和活性强度时的构象和动力学特性。具体来说,我们发现聚合物构象和单体动力学具有相关(或循环)长度的特征。相反,质量中心的动力学完全可以用端到端的均方距离和相关的弛豫时间来表征。因此,我们证明了极性活性聚合物熔体中单链的动力学不受缠结控制,而仅受自推进强度控制。
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来源期刊
CiteScore
10.40
自引率
3.40%
发文量
209
审稿时长
1 months
期刊介绍: ACS Macro Letters publishes research in all areas of contemporary soft matter science in which macromolecules play a key role, including nanotechnology, self-assembly, supramolecular chemistry, biomaterials, energy generation and storage, and renewable/sustainable materials. Submissions to ACS Macro Letters should justify clearly the rapid disclosure of the key elements of the study. The scope of the journal includes high-impact research of broad interest in all areas of polymer science and engineering, including cross-disciplinary research that interfaces with polymer science. With the launch of ACS Macro Letters, all Communications that were formerly published in Macromolecules and Biomacromolecules will be published as Letters in ACS Macro Letters.
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