Stability of electrocatalytic OER: from principle to application

Abstract

Hydrogen energy, derived from the electrolysis of water using renewable energy sources such as solar, wind, and hydroelectric power, is considered a promising form of energy to address the energy crisis. However, the anodic oxygen evolution reaction (OER) poses limitations due to sluggish kinetics. Apart from high catalytic activity, the long-term stability of electrocatalytic OER has garnered significant attention. To date, several research studies have been conducted to explore stable electrocatalysts for the OER. A comprehensive review is urgently warranted to provide a concise overview of the recent advancements in the electrocatalytic OER stability, encompassing both electrocatalyst and device developments. This review aims to succinctly summarize the primary factors influencing OER stability, including morphological/phase change and electrocatalyst dissolution, as well as mechanical detachment, alongside chemical, mechanical, and operational degradation observed in devices. Furthermore, an overview of contemporary approaches to enhance stability is provided, encompassing electrocatalyst design (structural regulation, protective layer coating, and stable substrate anchoring) and device optimization (bipolar plates, gas diffusion layers, and membranes). Hopefully, more attention will be paid to ensuring the stable operation of electrocatalytic OER and the future large-scale water electrolysis applications. This review presents design principles aimed at addressing challenges related to the stability of electrocatalytic OER.