Photoredox-catalyzed difunctionalization of alkenes with quinoxalinone and chloroform

IF 3.9 2区化学 Q2 CHEMISTRY, PHYSICAL

Molecular Catalysis Pub Date : 2024-09-13 DOI:10.1016/j.mcat.2024.114546

引用次数: 0

Abstract

A novel visible-light-induced multicomponent reaction of alkene with chloroform and quinoxalinone have been realized via a photocatalytic single electron transfer (SET). This protocol presents an efficient approach for the introduction of chloroalkyl motifs into N-heteroarenes. Meanwhile, this process features good functional group tolerance, and providing the corresponding products in moderate to good yields.

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光氧化催化烯与喹喔啉酮和氯仿的双官能化反应

通过光催化单电子转移（SET），实现了一种新颖的可见光诱导的烯与氯仿和喹喔啉酮的多组分反应。该方案提供了一种将氯烷基基团引入 N-teroarenes 的有效方法。同时，该工艺具有良好的官能团耐受性，并能以中等至良好的收率提供相应的产物。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Molecular Catalysis Chemical Engineering-Process Chemistry and Technology

CiteScore

6.90

自引率

10.90%

发文量

700

审稿时长

40 days

期刊介绍： Molecular Catalysis publishes full papers that are original, rigorous, and scholarly contributions examining the molecular and atomic aspects of catalytic activation and reaction mechanisms. The fields covered are: Heterogeneous catalysis including immobilized molecular catalysts Homogeneous catalysis including organocatalysis, organometallic catalysis and biocatalysis Photo- and electrochemistry Theoretical aspects of catalysis analyzed by computational methods