Fabrication of a cost-effective metal oxide-based adsorbent from industrial waste slag for efficient CO2 separation under flue gas conditions

Abstract

Efficient and affordable adsorbents for CO₂ capture are essential in implementing carbon capture technology to mitigate the negative impact of greenhouse gas emissions. This study focuses on synthesizing new nanoporous adsorbents from industrial waste slag using a simple and cost-effective coprecipitation method. In this method, raw slag was milled for 48 h and used as a benchmark for comparing two newly synthesized adsorbents. Selectivity and pure gas isotherm experiments were conducted for all adsorbents in the 25–65°C temperature range and under harsh industrial conditions of 65°C and 15 % CO₂. This study utilized the response surface methodology (RSM) to optimize the CO₂ adsorption parameters. Specifically, the optimized adsorption conditions were determined for the 15/85 % CO₂/N₂ condition, and the optimal values for pressure and temperature were found to be 5 bar and 45°C, resulting in CO₂/N₂ selectivity of 5.65. The NH₃-slag adsorbent was identified as the superior choice based on its selectivity and maximum adsorption capacity. The maximum adsorption capacity and cyclic efficiency were determined to be 4.15 mmol/g and 98.1 %, respectively, at a temperature, pressure, and composition of 45°C, 5 bar, and 15 % CO₂. Isotherm and thermodynamic models were employed to further investigate the adsorption process. The isotherm results indicated that the adsorption of CO₂ by adsorbents occurred heterogeneously in patch-wise sites. Meanwhile, the thermodynamic parameters showed that the process was exothermic and spontaneous, with ΔH° falling below 20 (kJ/mol), showing physisorption phenomena.