Construction of ternary Sn/SnO2/nitrogen-doped carbon superstructures as anodes for advanced lithium-ion batteries

IF 9.5 2区 材料科学 Q1 CHEMISTRY, PHYSICAL
Zizhou Shen, Xiaotian Guo, Hongye Ding, Dianheng Yu, Yihao Chen, Nana Li, Huijie Zhou, Songtao Zhang, Jun Wu, Huan Pang
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Abstract

Pristine tin (Sn) and tin dioxide (SnO2) have sparked wide interest owing to their abundant resources and superior theoretical capacity. Nevertheless, the obvious volume expansion effect upon cycling and undesirable conductivity of Sn-based materials lead to undesirable specific capacity. In this work, a nanostructured Sn/SnO2/nitrogen-doped carbon (NC) superstructure was prepared through a facile electrospray-carbonization strategy. The Sn/SnO2 nanoparticles (NPs) were uniformly dispersed in a spherical NC matrix, which prevented the volume expansion and aggregation of NPs and facilitated the ion diffusion and charge transfer kinetics. When the optimized Sn/SnO2/NC superstructures were employed as lithium-ion battery anodes, a remarkable specific capacity of 747.9 mAh·g−1 over 200 cycles at 0.5 A·g−1 and a superior cyclability of 644.1 mAh·g−1 over 1000 cycles at 2 A·g−1 were obtained. This effective synthetic strategy for synthesizing superstructures provides valuable insights for the advancement of lithium-ion batteries.

Abstract Image

构建作为先进锂离子电池阳极的三元锡/二氧化锰/掺氮碳上层结构
原始锡(Sn)和二氧化锡(SnO2)因其丰富的资源和卓越的理论容量而引发了广泛的兴趣。然而,锡基材料在循环过程中明显的体积膨胀效应和不理想的导电性导致了不理想的比容量。在这项工作中,通过一种简便的电喷雾碳化策略制备了一种纳米结构的 Sn/SnO2/ 掺氮碳(NC)上层结构。Sn/SnO2纳米颗粒(NPs)均匀地分散在球形的NC基体中,防止了NPs的体积膨胀和聚集,促进了离子扩散和电荷转移动力学。将优化后的 Sn/SnO2/NC 超结构用作锂离子电池阳极时,在 0.5 A-g-1 条件下循环 200 次可获得 747.9 mAh-g-1 的显著比容量,在 2 A-g-1 条件下循环 1000 次可获得 644.1 mAh-g-1 的卓越循环性。这种合成超结构的有效合成策略为锂离子电池的发展提供了宝贵的启示。
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来源期刊
Nano Research
Nano Research 化学-材料科学:综合
CiteScore
14.30
自引率
11.10%
发文量
2574
审稿时长
1.7 months
期刊介绍: Nano Research is a peer-reviewed, international and interdisciplinary research journal that focuses on all aspects of nanoscience and nanotechnology. It solicits submissions in various topical areas, from basic aspects of nanoscale materials to practical applications. The journal publishes articles on synthesis, characterization, and manipulation of nanomaterials; nanoscale physics, electrical transport, and quantum physics; scanning probe microscopy and spectroscopy; nanofluidics; nanosensors; nanoelectronics and molecular electronics; nano-optics, nano-optoelectronics, and nano-photonics; nanomagnetics; nanobiotechnology and nanomedicine; and nanoscale modeling and simulations. Nano Research offers readers a combination of authoritative and comprehensive Reviews, original cutting-edge research in Communication and Full Paper formats. The journal also prioritizes rapid review to ensure prompt publication.
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