A review on metal halide–ammonia thermochemical seasonal sorption energy storage systems

IF 3 3区 工程技术 Q2 CHEMISTRY, ANALYTICAL
Mostafa M. Salama, Sherif A. Mohamed, Mohamed Attalla, Ahmed N. Shmroukh
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Abstract

Energy storage has been proposed as a promising solution to reduce the mismatch between the energy supply and demand. Research on thermochemical sorption energy storage (TSES) has demonstrated considerable interest in thermal energy storage system and heat transforming processes used in applications of solar energy storage, space heating, industrial heat recovery, and heat upgrade during the past 20 years. TSES is the only promising method to store energy for long-term/seasonal periods without any energy losses. However, TSES system is more complex and thus has not yet been developed commercially. So, more efforts are required to bring this technology to the market. TSES is the most recent thermal energy storage technology in recent decades, and it is still under investigation in laboratories. Sorption materials are the basis for developing TSES systems; however, it has the drawbacks of agglomeration and swelling; to address this issue, porous heat transfer matrixes using expanded natural graphite (ENG) have recently been proposed for improving mass and heat transfer by solidified composite adsorbents. So, the techniques of making composites of inorganic salts for TSES systems are presented in detail. Different from previous reviews, this review article focuses on various solid–gas thermochemical seasonal sorption and resorption energy storage systems based on metal halide–ammonia and consolidated composite metal halide–ammonia working pairs. This paper provided a state-of-the-art review on the progress of the latest studies and projects of theoretical and experimental chemisorption energy storage systems. Basic concepts, Clapeyron diagram, and selection criteria of storage materials of TSES systems were also presented.

Abstract Image

金属卤化物-氨热化学季节性吸附储能系统综述
储能被认为是减少能源供需不匹配的一种有前途的解决方案。在过去 20 年中,热化学吸附储能(TSES)研究在太阳能储能、空间供热、工业用热回收和热能升级等应用领域的热能储存系统和热转换过程中表现出了极大的兴趣。TSES 是唯一有希望实现长期/季节性储能且无任何能量损失的方法。然而,TSES 系统较为复杂,因此尚未进行商业开发。因此,要将这项技术推向市场,还需要付出更多努力。TSES 是近几十年来最新的热能储存技术,目前仍在实验室中进行研究。吸附材料是开发 TSES 系统的基础,但它存在结块和膨胀的缺点;为了解决这个问题,最近有人提出了使用膨胀天然石墨(ENG)的多孔传热基质,以改善固化复合吸附剂的传质和传热。因此,本文详细介绍了用于 TSES 系统的无机盐复合材料的制作技术。与以往的综述不同,这篇综述文章重点介绍了基于金属卤化物-氨和固化复合金属卤化物-氨工作对的各种固气热化学季节性吸附和重吸收储能系统。本文对理论和实验化学吸附储能系统的最新研究和项目进展进行了最新综述。此外,还介绍了 TSES 系统的基本概念、克拉皮隆图和存储材料的选择标准。
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来源期刊
CiteScore
8.50
自引率
9.10%
发文量
577
审稿时长
3.8 months
期刊介绍: Journal of Thermal Analysis and Calorimetry is a fully peer reviewed journal publishing high quality papers covering all aspects of thermal analysis, calorimetry, and experimental thermodynamics. The journal publishes regular and special issues in twelve issues every year. The following types of papers are published: Original Research Papers, Short Communications, Reviews, Modern Instruments, Events and Book reviews. The subjects covered are: thermogravimetry, derivative thermogravimetry, differential thermal analysis, thermodilatometry, differential scanning calorimetry of all types, non-scanning calorimetry of all types, thermometry, evolved gas analysis, thermomechanical analysis, emanation thermal analysis, thermal conductivity, multiple techniques, and miscellaneous thermal methods (including the combination of the thermal method with various instrumental techniques), theory and instrumentation for thermal analysis and calorimetry.
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