Comparative analysis of kinetic-free thermal runaway criteria for semi-batch isoperibolic homogeneous exothermic reaction

IF 3 3区 工程技术 Q2 CHEMISTRY, ANALYTICAL
Rui Zhou, Ya-ting Chen, Jing-jing Xu, Jia-jia Jiang, Cui-mei Bo
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Abstract

For the semi-batch isoperibolic homogeneous exothermic reaction, the dosing rate is an effective method to control the exothermic rate. In this work, the esterification of propionic anhydride and sec-butanol is taken as an example to obtain the heat of reaction by considering the heat of mixing effect. The effect of dosing rates on reaction temperature and heat transfer efficiency are investigated for the semi-batch reaction system. The dosing rate is optimized by kinetic-free thermal runaway criteria based on Ψ number and the νADaREκ-Xac,max & Rymin-Wt plots. The effect of cooling jacket temperature on the optimal dosing rates calculated by the criteria is investigated. The obtained results have been compared with the boundary and temperature diagrams criterion. The results show that safe operation conditions can be approximately obtained when lack of kinetic information for semi-batch reaction process. This work can provide a guidance which can facilitate the optimization of dosing rate to improve reaction efficiency and prevent thermal runaway.

Abstract Image

半批次等容均质放热反应的无动力学热失控标准比较分析
对于半批次等容均相放热反应,加料速率是控制放热速率的有效方法。本研究以丙酸酐和仲丁醇的酯化反应为例,通过考虑混合热效应获得反应热。在半间歇反应系统中,研究了加料速率对反应温度和传热效率的影响。根据Ψ数和νADaREκ-Xac,max & Rymin-Wt图,采用无动力学热失控标准对加料速率进行了优化。研究了冷却套温度对根据该标准计算出的最佳配料率的影响。所得结果与边界图和温度图标准进行了比较。结果表明,在缺乏半批次反应过程动力学信息的情况下,可以大致获得安全的操作条件。这项工作可为优化配料率提供指导,从而提高反应效率并防止热失控。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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来源期刊
CiteScore
8.50
自引率
9.10%
发文量
577
审稿时长
3.8 months
期刊介绍: Journal of Thermal Analysis and Calorimetry is a fully peer reviewed journal publishing high quality papers covering all aspects of thermal analysis, calorimetry, and experimental thermodynamics. The journal publishes regular and special issues in twelve issues every year. The following types of papers are published: Original Research Papers, Short Communications, Reviews, Modern Instruments, Events and Book reviews. The subjects covered are: thermogravimetry, derivative thermogravimetry, differential thermal analysis, thermodilatometry, differential scanning calorimetry of all types, non-scanning calorimetry of all types, thermometry, evolved gas analysis, thermomechanical analysis, emanation thermal analysis, thermal conductivity, multiple techniques, and miscellaneous thermal methods (including the combination of the thermal method with various instrumental techniques), theory and instrumentation for thermal analysis and calorimetry.
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