Rui Zhou, Ya-ting Chen, Jing-jing Xu, Jia-jia Jiang, Cui-mei Bo
{"title":"Comparative analysis of kinetic-free thermal runaway criteria for semi-batch isoperibolic homogeneous exothermic reaction","authors":"Rui Zhou, Ya-ting Chen, Jing-jing Xu, Jia-jia Jiang, Cui-mei Bo","doi":"10.1007/s10973-024-13517-6","DOIUrl":null,"url":null,"abstract":"<p>For the semi-batch isoperibolic homogeneous exothermic reaction, the dosing rate is an effective method to control the exothermic rate. In this work, the esterification of propionic anhydride and <i>sec</i>-butanol is taken as an example to obtain the heat of reaction by considering the heat of mixing effect. The effect of dosing rates on reaction temperature and heat transfer efficiency are investigated for the semi-batch reaction system. The dosing rate is optimized by kinetic-free thermal runaway criteria based on Ψ number and the <i>ν</i><sub>A</sub>DaRE<i>κ-X</i><sub>ac,max</sub> & Ry<sub>min</sub>-Wt plots. The effect of cooling jacket temperature on the optimal dosing rates calculated by the criteria is investigated. The obtained results have been compared with the boundary and temperature diagrams criterion. The results show that safe operation conditions can be approximately obtained when lack of kinetic information for semi-batch reaction process. This work can provide a guidance which can facilitate the optimization of dosing rate to improve reaction efficiency and prevent thermal runaway.</p>","PeriodicalId":678,"journal":{"name":"Journal of Thermal Analysis and Calorimetry","volume":null,"pages":null},"PeriodicalIF":3.0000,"publicationDate":"2024-08-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Thermal Analysis and Calorimetry","FirstCategoryId":"5","ListUrlMain":"https://doi.org/10.1007/s10973-024-13517-6","RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, ANALYTICAL","Score":null,"Total":0}
引用次数: 0
Abstract
For the semi-batch isoperibolic homogeneous exothermic reaction, the dosing rate is an effective method to control the exothermic rate. In this work, the esterification of propionic anhydride and sec-butanol is taken as an example to obtain the heat of reaction by considering the heat of mixing effect. The effect of dosing rates on reaction temperature and heat transfer efficiency are investigated for the semi-batch reaction system. The dosing rate is optimized by kinetic-free thermal runaway criteria based on Ψ number and the νADaREκ-Xac,max & Rymin-Wt plots. The effect of cooling jacket temperature on the optimal dosing rates calculated by the criteria is investigated. The obtained results have been compared with the boundary and temperature diagrams criterion. The results show that safe operation conditions can be approximately obtained when lack of kinetic information for semi-batch reaction process. This work can provide a guidance which can facilitate the optimization of dosing rate to improve reaction efficiency and prevent thermal runaway.
期刊介绍:
Journal of Thermal Analysis and Calorimetry is a fully peer reviewed journal publishing high quality papers covering all aspects of thermal analysis, calorimetry, and experimental thermodynamics. The journal publishes regular and special issues in twelve issues every year. The following types of papers are published: Original Research Papers, Short Communications, Reviews, Modern Instruments, Events and Book reviews.
The subjects covered are: thermogravimetry, derivative thermogravimetry, differential thermal analysis, thermodilatometry, differential scanning calorimetry of all types, non-scanning calorimetry of all types, thermometry, evolved gas analysis, thermomechanical analysis, emanation thermal analysis, thermal conductivity, multiple techniques, and miscellaneous thermal methods (including the combination of the thermal method with various instrumental techniques), theory and instrumentation for thermal analysis and calorimetry.