Low-temperature performance of Na-ion batteries

IF 19.5 1区 材料科学 Q1 CHEMISTRY, PHYSICAL
Carbon Energy Pub Date : 2024-08-13 DOI:10.1002/cey2.546
Meng Li, Haoxiang Zhuo, Qihang Jing, Yang Gu, Zhou Liao, Kuan Wang, Jiangtao Hu, Dongsheng Geng, Xueliang Sun, Biwei Xiao
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Abstract

Sodium-ion batteries (NIBs) have become an ideal alternative to lithium-ion batteries in the field of electrochemical energy storage due to their abundant raw materials and cost-effectiveness. With the progress of human society, the requirements for energy storage systems in extreme environments, such as deep-sea exploration, aerospace missions, and tunnel operations, have become more stringent. The comprehensive performance of NIBs at low temperatures (LTs) has also become an important consideration. Under LT conditions, challenges such as increased viscosity of electrolyte, abnormal growth of solid electrolyte interface, and poor contact between collector and electrode materials emerge. The aforementioned issues hinder the diffusion kinetics of sodium ions (Na+) at the electrode/electrolyte interface and cause rapid degradation of battery performance. Consequently, the optimization of electrolyte composition and cathode/anode materials becomes an effective approach to improve LT performance. This review discusses the conduction behavior and limiting factors of Na+ in both solid electrodes and liquid electrolytes at LT. Furthermore, it systematically reviews the recent research progress of LT NIBs from three aspects: cathode materials, anode materials, and electrolyte components. This review aims to provide a valuable reference for developing high-performance LT NIBs.

Abstract Image

Abstract Image

钠离子电池的低温性能
在电化学储能领域,钠离子电池(NIB)以其丰富的原材料和成本效益成为锂离子电池的理想替代品。随着人类社会的进步,深海探测、航天任务、隧道作业等极端环境对储能系统的要求越来越严格。NIB 在低温条件下的综合性能也成为一个重要的考虑因素。在低温条件下,会出现电解质粘度增加、固体电解质界面异常生长、集电极和电极材料接触不良等挑战。上述问题阻碍了钠离子(Na+)在电极/电解质界面的扩散动力学,并导致电池性能迅速下降。因此,优化电解质成分和阴极/阳极材料成为提高 LT 性能的有效方法。本综述讨论了固态电极和液态电解质中 Na+ 在低温下的传导行为和限制因素。此外,它还从阴极材料、阳极材料和电解质成分三个方面系统地综述了近来有关低温无损探伤的研究进展。本综述旨在为开发高性能低温无离子电极提供有价值的参考。
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来源期刊
Carbon Energy
Carbon Energy Multiple-
CiteScore
25.70
自引率
10.70%
发文量
116
审稿时长
4 weeks
期刊介绍: Carbon Energy is an international journal that focuses on cutting-edge energy technology involving carbon utilization and carbon emission control. It provides a platform for researchers to communicate their findings and critical opinions and aims to bring together the communities of advanced material and energy. The journal covers a broad range of energy technologies, including energy storage, photocatalysis, electrocatalysis, photoelectrocatalysis, and thermocatalysis. It covers all forms of energy, from conventional electric and thermal energy to those that catalyze chemical and biological transformations. Additionally, Carbon Energy promotes new technologies for controlling carbon emissions and the green production of carbon materials. The journal welcomes innovative interdisciplinary research with wide impact. It is indexed in various databases, including Advanced Technologies & Aerospace Collection/Database, Biological Science Collection/Database, CAS, DOAJ, Environmental Science Collection/Database, Web of Science and Technology Collection.
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