Acrylonitrile styrene acrylate (ASA) treated jute/manila hemp epoxy-based hybrid composites for enhanced structural performance

IF 2.4 3区 化学 Q3 POLYMER SCIENCE
Mukesh Kumar Nag
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Abstract

The efficacy of a 3% ASA copolymer is examined in augmenting the mechanical properties of natural fiber composites. The batching process, which includes softening, lubricating, and conditioning, is applied in fibers, such as woven jute and non-woven manila hemp. This process is employed in the development of woven jute/epoxy, non-woven manila hemp/epoxy, and combined woven jute/non-woven manila hemp/epoxy composites to investigate their impact on their mechanical characteristics. Through various characterization methods, it was found that significant enhancements were observed in hybrid composites, particularly in the woven jute/non-woven manila hemp/epoxy composite. These enhancements include a maximum tensile strength of 52 MPa, a tensile modulus of 1.67 GPa, an impact strength of 9.6 kJ/m2, and a flexural strength of 90 MPa. The observed improvements are attributed to the influence of a hard chain copolymer, with a glass transition temperature of 25.05 °C determined from differential scanning calorimetry (DSC) curves. Fiber surface treatment using a semi-continuous seeded emulsion polymerization method significantly impacts properties, enhancing fiber–matrix adhesion and mechanical performance, resulting in a 14% increase in both tensile and flexural modulus compared to untreated composites. Analytical techniques such as emulsion particle-size measurements using dynamic light scattering (DLS) and SEM further support these findings.

Graphical abstract

Abstract Image

经丙烯腈-苯乙烯-丙烯酸酯 (ASA) 处理的黄麻/马尼拉麻环氧基混合复合材料可提高结构性能
摘要 研究了 3% ASA 共聚物在增强天然纤维复合材料机械性能方面的功效。配料工艺包括软化、润滑和调理,适用于纤维,如编织黄麻和无纺马尼拉麻。在开发黄麻/环氧树脂、马尼拉麻/环氧树脂无纺布以及黄麻/马尼拉麻/环氧树脂无纺布复合材料时采用了这一工艺,以研究它们对其机械特性的影响。通过各种表征方法发现,混合复合材料的机械性能显著提高,尤其是在黄麻/无纺马尼拉麻/环氧树脂复合材料中。这些增强包括 52 兆帕的最大拉伸强度、1.67 GPa 的拉伸模量、9.6 kJ/m2 的冲击强度和 90 兆帕的弯曲强度。观察到的改进归因于硬链共聚物的影响,根据差示扫描量热法(DSC)曲线测定,硬链共聚物的玻璃化转变温度为 25.05 °C。采用半连续种子乳液聚合法进行的纤维表面处理对性能产生了显著影响,增强了纤维与基体的粘附性和机械性能,与未经处理的复合材料相比,拉伸和弯曲模量均提高了 14%。使用动态光散射(DLS)和扫描电镜测量乳液粒度等分析技术进一步证实了这些发现。
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来源期刊
Iranian Polymer Journal
Iranian Polymer Journal 化学-高分子科学
CiteScore
4.90
自引率
9.70%
发文量
107
审稿时长
2.8 months
期刊介绍: Iranian Polymer Journal, a monthly peer-reviewed international journal, provides a continuous forum for the dissemination of the original research and latest advances made in science and technology of polymers, covering diverse areas of polymer synthesis, characterization, polymer physics, rubber, plastics and composites, processing and engineering, biopolymers, drug delivery systems and natural polymers to meet specific applications. Also contributions from nano-related fields are regarded especially important for its versatility in modern scientific development.
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