Electrodeposition of Cu2FeSnS4 thin films for solar cell applications: mechanism of deposition and influence of Fe2+ concentration

IF 2.6 4区 化学 Q3 ELECTROCHEMISTRY
Omar Ait Layachi, Abderrazzak Boudouma, Hala Hrir, Sara Azmi, Yousra Fariat, Imane Battiwa, Asmaa Moujib, El Mati Khoumri
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Abstract

In this study, we successfully synthesized semiconductor thin films of Cu2FeSnS4 (CFTS) using the electrodeposition method. We delved into the mechanisms of electrochemical nucleation and growth, shedding light on these processes. Utilizing potentiostatic current-density-time transient measurements and in situ electrochemical impedance spectroscopy (EIS), we explored the nucleation and growth mechanisms of Cu2FeSnS4 (CFTS) thin films, deposited from an aqueous solution under various applied potentials. Cyclic voltammetry was employed to investigate the electrochemical behaviors of Cu-Fe-Sn-S precursors in a trisodium citrate medium. Chronoamperometry and EIS analysis were conducted to delve deeply into the deposition mechanism and surface electrode-electrolyte phenomena. Furthermore, the study explored the impact of Fe2+ concentration on structural morphology and optical properties. X-ray diffraction and Raman analysis unveiled the stannite structure within the obtained Cu2FeSnS4 thin film, alongside the presence of secondary phases in the CFTS elaborated at both lower and higher concentrations of Fe2+. SEM images reveal that the sulfurized CFTS C2 (0.01 M of Fe2+) sample has a surface morphology with irregular particles. EDS mapping and EDX analysis confirm that the elemental concentrations of Cu, Fe, Sn, and S in the CFTS C2 thin films closely match the desired stoichiometry for Cu2FeSnS4. UV-visible spectroscopy revealed a suitable bandgap energy within the range of 1.5 eV for the film deposited with a Fe2+ concentration of 0.01 M.

Graphical Abstract

Abstract Image

用于太阳能电池的 Cu2FeSnS4 薄膜的电沉积:沉积机理和 Fe2+ 浓度的影响
在这项研究中,我们采用电沉积法成功合成了 Cu2FeSnS4(CFTS)半导体薄膜。我们深入研究了电化学成核和生长机制,揭示了这些过程。利用恒电位电流密度-时间瞬态测量和原位电化学阻抗谱(EIS),我们探索了在不同应用电位下从水溶液中沉积的 Cu2FeSnS4 (CFTS) 薄膜的成核和生长机制。我们采用循环伏安法研究了 Cu-Fe-Sn-S 前驱体在柠檬酸三钠介质中的电化学行为。为了深入研究沉积机理和表面电极-电解质现象,还进行了时变测量和 EIS 分析。此外,研究还探讨了 Fe2+ 浓度对结构形态和光学特性的影响。X 射线衍射和拉曼分析揭示了所获得的 Cu2FeSnS4 薄膜中的锡石结构,以及在较低和较高的 Fe2+ 浓度下制备的 CFTS 中存在的次生相。SEM 图像显示,硫化 CFTS C2(0.01 M Fe2+)样品的表面形态为不规则颗粒。EDS 图谱和 EDX 分析证实,CFTS C2 薄膜中的铜、铁、锡和 S 元素浓度非常符合 Cu2FeSnS4 的理想化学计量。紫外可见光谱显示,在 Fe2+ 浓度为 0.01 M 时沉积的薄膜具有 1.5 eV 范围内的合适带隙能。
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来源期刊
CiteScore
4.80
自引率
4.00%
发文量
227
审稿时长
4.1 months
期刊介绍: The Journal of Solid State Electrochemistry is devoted to all aspects of solid-state chemistry and solid-state physics in electrochemistry. The Journal of Solid State Electrochemistry publishes papers on all aspects of electrochemistry of solid compounds, including experimental and theoretical, basic and applied work. It equally publishes papers on the thermodynamics and kinetics of electrochemical reactions if at least one actively participating phase is solid. Also of interest are articles on the transport of ions and electrons in solids whenever these processes are relevant to electrochemical reactions and on the use of solid-state electrochemical reactions in the analysis of solids and their surfaces. The journal covers solid-state electrochemistry and focusses on the following fields: mechanisms of solid-state electrochemical reactions, semiconductor electrochemistry, electrochemical batteries, accumulators and fuel cells, electrochemical mineral leaching, galvanic metal plating, electrochemical potential memory devices, solid-state electrochemical sensors, ion and electron transport in solid materials and polymers, electrocatalysis, photoelectrochemistry, corrosion of solid materials, solid-state electroanalysis, electrochemical machining of materials, electrochromism and electrochromic devices, new electrochemical solid-state synthesis. The Journal of Solid State Electrochemistry makes the professional in research and industry aware of this swift progress and its importance for future developments and success in the above-mentioned fields.
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