Unlocking the value of food waste: sustainable production of ethylene glycol over low-cost Ni–W catalysts supported on glucose-derived carbons†

IF 5 3区 材料科学 Q2 CHEMISTRY, PHYSICAL
Lucília Sousa Ribeiro, Rafael Gomes Morais, José Joaquim de Melo Órfão and Manuel Fernando Ribeiro Pereira
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Abstract

Food waste is abundant and holds great potential to be converted into valuable chemicals like ethylene glycol (EG), which is a key compound for the production of commodity polymers and other specialty products. Therefore, the direct conversion of food waste could represent a pivotal alternative for the sustainable production of EG. Nickel-tungsten catalysts supported on glucose-derived carbons were synthesized and evaluated for EG direct production from cellulose and cellulosic urban wastes. A remarkable yield of EG of 62% was attained directly from cellulose after 5 h, while the optimized catalyst allowed to reach notable EG yields around 40% from cellulosic wastes. Furthermore, as far as we are concerned, no previous works have reported the conversion of food wastes, such as fruit peels, directly into EG. Therefore, we report the environmentally friendly production of EG from banana peel, orange peel and spent coffee grounds with promising yields of up to 21%.

Abstract Image

Abstract Image

释放食物垃圾的价值:利用葡萄糖衍生碳支撑的低成本 Ni-W 催化剂可持续生产乙二醇
厨余垃圾数量丰富,具有将其转化为乙二醇(EG)等有价值化学品的巨大潜力,而乙二醇是生产商品聚合物和其他特种产品的关键化合物。因此,直接转化食物垃圾可能是可持续生产乙二醇的关键替代方法。我们合成并评估了以葡萄糖衍生碳为载体的镍钨催化剂,用于从纤维素和纤维素城市废物中直接生产 EG。5 小时后,直接从纤维素中获得了 62% 的显著 EG 产量,而优化后的催化剂可从纤维素废料中获得约 40% 的显著 EG 产量。此外,就我们所知,之前还没有任何关于将果皮等食物垃圾直接转化为 EG 的报道。因此,我们报告了利用香蕉皮、橘子皮和用过的咖啡渣生产 EG 的环境友好型方法,产量有望达到 21%。
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来源期刊
Sustainable Energy & Fuels
Sustainable Energy & Fuels Energy-Energy Engineering and Power Technology
CiteScore
10.00
自引率
3.60%
发文量
394
期刊介绍: Sustainable Energy & Fuels will publish research that contributes to the development of sustainable energy technologies with a particular emphasis on new and next-generation technologies.
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