Feasibility study on conversion of biowaste of lemon peel into carbon electrode for supercapacitor using ZnCl2 as an activating agent

Abstract

Here, we describe the analysis of the capacitive performance of activated carbon materials derived from the biowaste of lemon. Lemon peel discarded by restaurants after juice extraction is carbonized at 400 ⁰C followed by chemical activation using ZnCl₂. The porosity of carbon materials is tailored by varying activation conditions, such as the mass ratio of carbonized lemon peel and ZnCl₂, duration of heating, and temperature. The Brunauer–Emmett– Teller (BET) surface area and pore volume of carbon materials prepared at different activating conditions range from 1380 to 2120 m²g⁻¹ and 0.38 to 0.69 cm³ g⁻¹ respectively. The derived carbon materials are amorphous indicated by the broad peaks in the XRD pattern as well as disordered structure of the carbon materials is revealed by the Raman spectroscopic analysis. The systematic analysis of capacitive performance of activated carbons by employing electrochemical techniques like Cyclic Voltammetry (CV), Galvanostatic charge/Discharge (GCD) cycles, and electrochemical impedance spectroscopy (EIS) in acidic (H₂SO₄) and alkaline (KOH) media indicates that optimum condition for activation of lemon peel is 600 °C for 60 min with 1:1 mass ratio of carbonized lemon peel and ZnCl₂. The superior performance of (ALP-600) is attributed to its high surface area and well-connected hierarchical porous structure. The tiny hump at ~ 0.2 V in CV might be due to the pseudocapacitive nature of oxygen functional groups indicated by FTIR. ALP-600 exhibits the highest specific capacitance of 180 Fg⁻¹ and retains 99.7% of its initial capacitance after 5000 cycles in the acidic electrolyte. The maximum capacitance achieved with ALP-600 symmetric cell in CR2032 coin cell configuration is 0.90F.