Probing the limits of tetraalkylthiuram disulfide synthesis by direct reaction of secondary amines with CS2: The structures of Cy2NC(S)SSC(S)NCy2 and Cy2NC(S)SSSSC(S)NCy2

Saikat Mishra, Gayathri Ragunathan, Joel T. Mague, Xiaodong Zhang, James P. Donahue
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Abstract

Reaction of Cy2NH with CS2 in NaOH/H2O, followed by oxidation with I2, yields a complex mixture that includes the tetracyclohexylthiuram disulfide, Cy2NC(S)SSC(S)NCy2, in mixture with S8 and the te...
通过仲胺与 CS2 的直接反应探索四烷基秋兰姆二硫化物合成的极限:Cy2NC(S)SSC(S)NCy2 和 Cy2NC(S)SSSSC(S)NCy2 的结构
Cy2NH与CS2在NaOH/H2O中反应,然后与I2氧化,得到一种复杂的混合物,其中包括四环己基秋兰姆二硫化物Cy2NC(S)SSC(S)NCy2与S8的混合物,以及Te...
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