Design of a High-Performance WO3/g-C3N4 Z-Scheme Photocatalyst for Effective Phenol Degradation and Antibacterial Activity

IF 2.7 4区 化学 Q2 CHEMISTRY, INORGANIC & NUCLEAR
T. Prabhuraj, Abimannan Gomathi, Arumugam Priyadharsan, Murni Handayani, Sabah Ansar, K. A. Ramesh Kumar, Palanisamy Maadeswaran
{"title":"Design of a High-Performance WO3/g-C3N4 Z-Scheme Photocatalyst for Effective Phenol Degradation and Antibacterial Activity","authors":"T. Prabhuraj,&nbsp;Abimannan Gomathi,&nbsp;Arumugam Priyadharsan,&nbsp;Murni Handayani,&nbsp;Sabah Ansar,&nbsp;K. A. Ramesh Kumar,&nbsp;Palanisamy Maadeswaran","doi":"10.1007/s10876-024-02692-z","DOIUrl":null,"url":null,"abstract":"<div><p>An innovative Z-scheme WO<sub>3</sub>/g-C<sub>3</sub>N<sub>4</sub> composite was efficiently produced via a straightforward hydrothermal method and applied to the photodegradation of phenol. The physiochemical behaviours of WO<sub>3</sub>, g-C<sub>3</sub>N<sub>4</sub>, WO<sub>3</sub>/g-C<sub>3</sub>N<sub>4</sub> composite was analyzed by various analytical instruments. Compared to WO<sub>3</sub>, g-C<sub>3</sub>N<sub>4</sub> single counterparts WO<sub>3</sub>/g-C<sub>3</sub>N<sub>4</sub> Composite exhibits superior charge carriers’ separation efficiency and also Z scheme mechanism promoted the superior pollutant degradation. Subsequently, the WO<sub>3</sub>/g-C<sub>3</sub>N<sub>4</sub> composite achieving 93% with rate constant 0.0184 min<sup>− 1</sup> phenol removal within 100 min. The noteworthy increased photocatalytic bustle of WO<sub>3</sub>/g-C<sub>3</sub>N<sub>4</sub> composite was attributed to the synergetic effect between the boundary of WO<sub>3</sub>/g-C<sub>3</sub>N<sub>4</sub>. Curiously, WO<sub>3</sub>/g-C<sub>3</sub>N<sub>4</sub> composite validates exceptional photostability during reusable experiment, accentuating its potential as a functioning photocatalyst for phenol removal. The antimicrobial tests showed that the developed photocatalyst effectively sterilizes both gram-positive <i>Staphylococcus aureus</i> and gram-negative <i>Escherichia coli</i>. Thus, the WO<sub>3</sub>/g-C<sub>3</sub>N<sub>4</sub> nanocomposites are robust materials suitable for use as antimicrobial agents and photocatalysts activated by sunlight.</p></div>","PeriodicalId":618,"journal":{"name":"Journal of Cluster Science","volume":"35 8","pages":"2753 - 2768"},"PeriodicalIF":2.7000,"publicationDate":"2024-09-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Cluster Science","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s10876-024-02692-z","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
引用次数: 0

Abstract

An innovative Z-scheme WO3/g-C3N4 composite was efficiently produced via a straightforward hydrothermal method and applied to the photodegradation of phenol. The physiochemical behaviours of WO3, g-C3N4, WO3/g-C3N4 composite was analyzed by various analytical instruments. Compared to WO3, g-C3N4 single counterparts WO3/g-C3N4 Composite exhibits superior charge carriers’ separation efficiency and also Z scheme mechanism promoted the superior pollutant degradation. Subsequently, the WO3/g-C3N4 composite achieving 93% with rate constant 0.0184 min− 1 phenol removal within 100 min. The noteworthy increased photocatalytic bustle of WO3/g-C3N4 composite was attributed to the synergetic effect between the boundary of WO3/g-C3N4. Curiously, WO3/g-C3N4 composite validates exceptional photostability during reusable experiment, accentuating its potential as a functioning photocatalyst for phenol removal. The antimicrobial tests showed that the developed photocatalyst effectively sterilizes both gram-positive Staphylococcus aureus and gram-negative Escherichia coli. Thus, the WO3/g-C3N4 nanocomposites are robust materials suitable for use as antimicrobial agents and photocatalysts activated by sunlight.

Abstract Image

设计高性能 WO3/g-C3N4 Z-Scheme 光催化剂以实现有效的苯酚降解和抗菌活性
通过直接水热法高效制备了一种创新的 Z 型 WO3/g-C3N4 复合材料,并将其应用于苯酚的光降解。各种分析仪器对 WO3、g-C3N4 和 WO3/g-C3N4 复合材料的理化性能进行了分析。与 WO3 相比,g-C3N4 单体对应的 WO3/g-C3N4 复合体表现出更高的电荷载流子分离效率,同时 Z 方案机制也促进了更优越的污染物降解。随后,WO3/g-C3N4 复合材料在 100 分钟内对苯酚的去除率达到 93%,速率常数为 0.0184 min-1。值得注意的是,WO3/g-C3N4 复合材料光催化效率的提高归功于 WO3/g-C3N4 边界之间的协同效应。奇怪的是,WO3/g-C3N4 复合材料在可重复使用的实验中验证了其优异的光稳定性,突出了其作为有效光催化剂去除苯酚的潜力。抗菌测试表明,所开发的光催化剂可有效杀灭革兰氏阳性金黄色葡萄球菌和革兰氏阴性大肠杆菌。因此,WO3/g-C3N4 纳米复合材料是一种坚固的材料,适合用作抗菌剂和由阳光激活的光催化剂。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 求助全文
来源期刊
Journal of Cluster Science
Journal of Cluster Science 化学-无机化学与核化学
CiteScore
6.70
自引率
0.00%
发文量
166
审稿时长
3 months
期刊介绍: The journal publishes the following types of papers: (a) original and important research; (b) authoritative comprehensive reviews or short overviews of topics of current interest; (c) brief but urgent communications on new significant research; and (d) commentaries intended to foster the exchange of innovative or provocative ideas, and to encourage dialogue, amongst researchers working in different cluster disciplines.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信