Structural, Magnetic, and Electrical Properties in Ba-Doped BiFeO3 Prepared Using a Sol–Gel Route

IF 0.9 4区 物理与天体物理 Q4 PHYSICS, CONDENSED MATTER
Sachin D. Rajadhyax, Sangeeta G. Dahotre, Rajib Mondal, Umesh L. Shinde, Pranav P. Naik, Snehal Hasolkar
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引用次数: 0

Abstract

Ba-doped bismuth ferrite with chemical composition Bi1 – xBaxFeO3 (x = 0.1, 0.2, 0.3, 0.4, and 0.5) nanoparticles were synthesized by the wet chemical sol–gel method. The substitution of Ba2+ at the Bi3+ site was meant to improve the resistivity, enhance magnetic properties, and suppress the impurity phases of BiFeO3. The samples synthesized were later subjected to X-ray diffraction (XRD) analysis, Field emission scanning electron microscope (FESEM) with energy dispersive spectroscopy (EDS), Magnetic measurements using a vibrating sample magnetometer (VSM) and dielectric analysis along with ferroelectric measurements. XRD patterns obtained at room temperature revealed that the obtained samples are single-phase materials. The crystallite size showed a decrease from 46 to 24.58 nm and the unit cell volume was found to increase following Vegard’s law. The increase in tolerance factor from 0.855 to 0.908 was reported for increasing doping concentrations. The FESEM and SEM micrographs indicate that the particles are rhombohedral-hexagonal in shape. The EDS results confirm the presence of the desired elements Ba, Bi, Fe, and O and the proportionate composition of various elements present as well. The room temperature M–H curve and the M–H curve at 3 K also confirm the enhancement in magnetization with increasing doping concentration. The room temperature dielectric measurements reveal the improving resistivity of the samples with increasing doping concentrations. The increasing grain resistance as revealed by the Cole-Cole plots indicate the decreasing conductivity of doped BFO samples. The P–E measurements confirm the ferroelectric nature of the material.

Abstract Image

Abstract Image

采用溶胶-凝胶法制备的掺钡 BiFeO3 的结构、磁性和电性能
摘要 采用湿化学溶胶-凝胶法合成了化学成分为 Bi1 - xBaxFeO3(x = 0.1、0.2、0.3、0.4 和 0.5)的掺钡铋铁氧体纳米粒子。在 Bi3+ 位点取代 Ba2+ 的目的是提高 BiFeO3 的电阻率、增强磁性能并抑制杂质相。合成的样品随后进行了 X 射线衍射 (XRD) 分析、场发射扫描电子显微镜 (FESEM) 和能量色散光谱分析 (EDS)、使用振动样品磁力计 (VSM) 进行的磁性测量以及介电分析和铁电测量。室温下获得的 XRD 图谱显示,获得的样品是单相材料。晶粒大小从 46 纳米减小到 24.58 纳米,单位晶胞体积按照维加定律增大。随着掺杂浓度的增加,公差系数从 0.855 增加到 0.908。FESEM 和 SEM 显微照片显示,颗粒呈斜方六边形。EDS 结果证实了所需元素 Ba、Bi、Fe 和 O 的存在以及各种元素的比例组成。室温下的 M-H 曲线和 3 K 时的 M-H 曲线也证实了磁化率随着掺杂浓度的增加而增强。室温介电测量显示,随着掺杂浓度的增加,样品的电阻率也在提高。科尔-科尔曲线图显示的晶粒电阻增加表明,掺杂 BFO 样品的导电性降低。P-E 测量证实了材料的铁电性质。
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来源期刊
Physics of the Solid State
Physics of the Solid State 物理-物理:凝聚态物理
CiteScore
1.70
自引率
0.00%
发文量
60
审稿时长
2-4 weeks
期刊介绍: Presents the latest results from Russia’s leading researchers in condensed matter physics at the Russian Academy of Sciences and other prestigious institutions. Covers all areas of solid state physics including solid state optics, solid state acoustics, electronic and vibrational spectra, phase transitions, ferroelectricity, magnetism, and superconductivity. Also presents review papers on the most important problems in solid state physics.
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