Advances in bifunctional electro-responsive materials for superior energy-efficient electrochromic energy storage devices

IF 23.2 2区 材料科学 Q1 MATERIALS SCIENCE, COMPOSITES
Min Zhou, Fan Li, Jidong Dong, Shang Sun, Yuanyuan Zhu, Wenjing Zhang, Zhou Lu, Wei Zhang, Haijun Niu, Jiang Guo, Lina Ma, Yudong Huang
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Abstract

The ever-growing pressure from the energy crisis and environmental pollution has promoted the development of efficient multifunctional electric devices. The energy storage and multicolor electrochromic (EC) characteristics have gained tremendous attention for novel devices in the past several decades. The precise design of EC electroactive materials can facilitate the integration of electrochromic energy storage devices (EESDs). Such devices can be utilized not only for self-powering but also for intelligent sensing of real-time working conditions through various visualizations. In this review, we systematically introduce the concept, possibilities (electro-responsive materials, device structure, and state-switching time scale), working principles, and significant factors of EESDs. Subsequently, we comprehensively summarize the latest achievements in electro-responsive dual-functional materials, encompassing inorganic materials (transition metal oxides, Prussian blue, polyoxometalates, etc.), organic materials (small organic molecules, polymers, etc.), and hybrid materials (inorganic-inorganic hybrids, inorganic–organic hybrids). Our focus lies on structure/morphology engineering, doping techniques, and hybridization strategy design. Additionally, we illustrate the application of advanced multifunctional materials in various devices such as flexible, stretchable, self-powering, and artificial intelligence devices. Finally, we present the challenges, prospects, and opportunities of high-performance EESDs.

Graphical abstract

Abstract Image

双功能电响应材料在高能效电致变色储能设备中的应用进展
能源危机和环境污染带来的压力与日俱增,推动了高效多功能电动装置的发展。在过去的几十年里,储能和多色电致变色(EC)特性在新型设备中获得了极大的关注。电致变色电活性材料的精确设计可促进电致变色储能器件(EESD)的集成。这种装置不仅可以用于自供电,还可以通过各种可视化方式智能感知实时工作状态。在这篇综述中,我们系统地介绍了 EESD 的概念、可能性(电响应材料、器件结构和状态切换时间尺度)、工作原理和重要因素。随后,我们全面总结了电响应双功能材料的最新成果,包括无机材料(过渡金属氧化物、普鲁士蓝、聚氧金属盐等)、有机材料(有机小分子、聚合物等)和混合材料(无机-无机混合材料、无机-有机混合材料)。我们的重点是结构/形态工程、掺杂技术和杂化策略设计。此外,我们还说明了先进多功能材料在柔性、可拉伸、自供电和人工智能设备等各种设备中的应用。最后,我们介绍了高性能 EESD 的挑战、前景和机遇。
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来源期刊
CiteScore
26.00
自引率
21.40%
发文量
185
期刊介绍: Advanced Composites and Hybrid Materials is a leading international journal that promotes interdisciplinary collaboration among materials scientists, engineers, chemists, biologists, and physicists working on composites, including nanocomposites. Our aim is to facilitate rapid scientific communication in this field. The journal publishes high-quality research on various aspects of composite materials, including materials design, surface and interface science/engineering, manufacturing, structure control, property design, device fabrication, and other applications. We also welcome simulation and modeling studies that are relevant to composites. Additionally, papers focusing on the relationship between fillers and the matrix are of particular interest. Our scope includes polymer, metal, and ceramic matrices, with a special emphasis on reviews and meta-analyses related to materials selection. We cover a wide range of topics, including transport properties, strategies for controlling interfaces and composition distribution, bottom-up assembly of nanocomposites, highly porous and high-density composites, electronic structure design, materials synergisms, and thermoelectric materials. Advanced Composites and Hybrid Materials follows a rigorous single-blind peer-review process to ensure the quality and integrity of the published work.
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