Bo Yang, Hai-Jun Feng, Tian-Tian Ni, Xiao-Rui Zhou, Tao Xie, Ning Zheng
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引用次数: 0
Abstract
The incorporation of dynamic covalent bonds into thermosets facilitates the reprocessing of polymer networks, thereby meeting the sustainable requirements for polymer recycling. However, the mechanical properties of many materials often decline significantly upon reprocessing due to side reactions caused by harsh processing conditions. In this work, we find that the aromatic dithiocarbamate bond can undergo dissociation under mild conditions without the need for a catalyst, enabling the efficient reprocessing of the corresponding polydithiourethane. As a consequence, the mechanical properties of the polydithiourethane can be largely preserved after reprocessing. The discovery of this dynamic chemistry is anticipated to broaden the potential for material design in dynamic covalent polymer networks.
期刊介绍：
Chinese Journal of Polymer Science (CJPS) is a monthly journal published in English and sponsored by the Chinese Chemical Society and the Institute of Chemistry, Chinese Academy of Sciences. CJPS is edited by a distinguished Editorial Board headed by Professor Qi-Feng Zhou and supported by an International Advisory Board in which many famous active polymer scientists all over the world are included. The journal was first published in 1983 under the title Polymer Communications and has the current name since 1985.
CJPS is a peer-reviewed journal dedicated to the timely publication of original research ideas and results in the field of polymer science. The issues may carry regular papers, rapid communications and notes as well as feature articles. As a leading polymer journal in China published in English, CJPS reflects the new achievements obtained in various laboratories of China, CJPS also includes papers submitted by scientists of different countries and regions outside of China, reflecting the international nature of the journal.
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