Effect of Different AC Densities on Corrosion Resistance and Mechanism of FeCoNi HEA in Simulated Golmud Soil Environment

IF 2.2 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY
Q. H. Ni, M. Zhu, Y. F. Yuan, S. Y. Guo
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Abstract

The paper systematically studied the effect of AC density on corrosion resistance of FeCoNi HEA in simulated Golmud soil solution. The results imply that the applied iAC seriously decreases the anticorrosion property of the HEA. In particular, under high AC density, the active state is presented and the corrosion characteristic changes from slightly local pitting to uneven overall corrosion with massive large-sized corrosion pits. Moreover, after imposed AC of 100 A/m2, the honeycomb holes are produced within passive film, which suggests that AC severely damages the film integrity, and reduces the protection and stability of the film. This phenomenon is due to the reason that as iAC rises, more generated hydrogen ions/atoms and Cl are absorbed on the defect regions of passive film, significantly promoting the film dissolution, and facilitating the pitting initiation and development.

Abstract Image

不同交流电密度对模拟格尔木土壤环境中铁钴镍氢乙酸酯耐腐蚀性和机理的影响
本文系统研究了交流电密度对模拟格尔木土壤溶液中铁钴镍钴合金电弧炉耐腐蚀性能的影响。结果表明,外加的 iAC 会严重降低 HEA 的防腐性能。特别是在高交流电密度下,呈现出活跃状态,腐蚀特征从轻微的局部点蚀转变为不均匀的整体腐蚀,并伴有大量大尺寸腐蚀坑。此外,在施加 100 A/m2 的交流电后,被动膜内部会产生蜂窝状孔洞,这表明交流电严重破坏了膜的完整性,降低了膜的保护性和稳定性。出现这种现象的原因是随着 iAC 的升高,被动膜缺陷区域吸收了更多生成的氢离子/原子和 Cl-,大大促进了膜的溶解,有利于点蚀的产生和发展。
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来源期刊
Journal of Materials Engineering and Performance
Journal of Materials Engineering and Performance 工程技术-材料科学:综合
CiteScore
3.90
自引率
13.00%
发文量
1120
审稿时长
4.9 months
期刊介绍: ASM International''s Journal of Materials Engineering and Performance focuses on solving day-to-day engineering challenges, particularly those involving components for larger systems. The journal presents a clear understanding of relationships between materials selection, processing, applications and performance. The Journal of Materials Engineering covers all aspects of materials selection, design, processing, characterization and evaluation, including how to improve materials properties through processes and process control of casting, forming, heat treating, surface modification and coating, and fabrication. Testing and characterization (including mechanical and physical tests, NDE, metallography, failure analysis, corrosion resistance, chemical analysis, surface characterization, and microanalysis of surfaces, features and fractures), and industrial performance measurement are also covered
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