Direct Ion-Exchange Method for Preparing a Solution Allowing Spontaneous Perovskite Passivation via Hole Transport Material Deposition

IF 8.3 2区材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY

ACS Applied Materials & Interfaces Pub Date : 2024-09-11 DOI:10.1021/acsaem.4c01314

Naoyuki Nishimura, Hiroyuki Kanda, Takurou N. Murakami

引用次数: 0

Abstract

We propose a direct ion-exchange (DI) method for preparing a hole transport material (HTM) solution undergoing spontaneous perovskite passivation via HTM deposition and verify its applicability for the photovoltaic performance enhancement of perovskite solar cells (PSCs). The simple synthesis of a Spiro-OMeTAD HTM solution based on ion exchange via dissolving and mixing multiple solid materials in a chlorobenzene solution produces an HTM solution similar to that obtained with an n-octylammonium bis(trifluoromethanesulfonyl)imide ionic liquid functioning as a spontaneous perovskite passivator. Using the resulting HTM solution, the power conversion efficiency of PSCs was enhanced up to 23.0% without conventional postpassivation processes.

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直接离子交换法制备可通过孔传输材料沉积实现自发钝化的过氧化物溶液

我们提出了一种直接离子交换 (DI) 方法，用于制备通过 HTM 沉积实现自发包晶钝化的空穴传输材料 (HTM) 溶液，并验证了该方法在提高包晶太阳能电池 (PSC) 光电性能方面的适用性。通过在氯苯溶液中溶解和混合多种固体材料，在离子交换的基础上简单合成了螺-OMeTAD HTM 溶液，产生了一种 HTM 溶液，与作为自发包晶钝化剂的正辛基双(三氟甲磺酰)亚胺离子液体得到的 HTM 溶液相似。使用所得到的 HTM 溶液，无需传统的后钝化工艺，便可将 PSC 的功率转换效率提高到 23.0%。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

ACS Applied Materials & Interfaces 工程技术-材料科学：综合

CiteScore

16.00

自引率

6.30%

发文量

4978

审稿时长

1.8 months

期刊介绍： ACS Applied Materials & Interfaces is a leading interdisciplinary journal that brings together chemists, engineers, physicists, and biologists to explore the development and utilization of newly-discovered materials and interfacial processes for specific applications. Our journal has experienced remarkable growth since its establishment in 2009, both in terms of the number of articles published and the impact of the research showcased. We are proud to foster a truly global community, with the majority of published articles originating from outside the United States, reflecting the rapid growth of applied research worldwide.