Modification of aspen wood ethanol lignin via azo coupling: promising polymers from renewable plant biomass

IF 3.1 2区 农林科学 Q1 FORESTRY
Viktor A. Golubkov, Valentina S. Borovkova, Maxim A. Lutoshkin, Nikolay A. Zos’ko, Natalya Yu. Vasilieva, Yuriy N. Malyar
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引用次数: 0

Abstract

Plant biomass, in particular forestry wastes, is a promising renewable feedstock for deep chemical processing. Organosolv methods allow the use of underutilized lignin. The synthesis of modified polymers by azo coupling with the use of aspen (Populus tremula) ethanol lignin and its sulfated modification is studied. The success of the synthesis has been proven and the features of the structure and properties of the synthesized samples were studied by the physicochemical techniques, including Fourier transform infrared and nuclear magnetic resonance spectroscopy, gel permeation chromatography and thermogravimetric analysis. It was shown that the new azopolymers have the ability to photoisomerize, which opens up prospects for their high-tech applications. The modified lignins are proven to be bioactive antioxidants.

Abstract Image

通过偶氮偶联对杨木乙醇木质素进行改性:从可再生植物生物质中提取有前景的聚合物
植物生物质,尤其是林业废弃物,是一种很有前景的可再生原料,可用于化学深加工。有机溶胶法可以利用未充分利用的木质素。本研究利用杨树乙醇木质素及其硫酸化改性,通过偶氮偶联合成改性聚合物。通过傅立叶变换红外光谱、核磁共振光谱、凝胶渗透色谱和热重分析等理化技术研究了合成样品的结构和性质特征。研究表明,新型偶氮聚合物具有光异构化能力,这为其在高科技领域的应用开辟了前景。改性木质素被证明是具有生物活性的抗氧化剂。
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来源期刊
Wood Science and Technology
Wood Science and Technology 工程技术-材料科学:纸与木材
CiteScore
5.90
自引率
5.90%
发文量
75
审稿时长
3 months
期刊介绍: Wood Science and Technology publishes original scientific research results and review papers covering the entire field of wood material science, wood components and wood based products. Subjects are wood biology and wood quality, wood physics and physical technologies, wood chemistry and chemical technologies. Latest advances in areas such as cell wall and wood formation; structural and chemical composition of wood and wood composites and their property relations; physical, mechanical and chemical characterization and relevant methodological developments, and microbiological degradation of wood and wood based products are reported. Topics related to wood technology include machining, gluing, and finishing, composite technology, wood modification, wood mechanics, creep and rheology, and the conversion of wood into pulp and biorefinery products.
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