Abrasive Wear of Rubbers Based on Natural Rubber, Carbon Black, and Polyoxadiazole Fiber

IF 0.5 4区 工程技术 Q4 ENGINEERING, MECHANICAL
V. N. Aderikha, N. A. Marusenko
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引用次数: 0

Abstract

The influence of the abrasive particle size and modifiers (low molecular weight liquid rubbers (LMWRs), sulfidosilane) on the rate of wear on abrasive paper of rubbers based on natural rubber (NR), carbon black (CB), and polyoxadiazole (POD) fiber is studied as a function of structure and mechanical properties of rubbers. Model rubber blends were prepared in a closed-type mixer, the abrasive wear tests were conducted on a drum-type machine, the structure and the mechanical properties of rubbers were characterized by DMA, static tensile tests, hardness measurements, and tear resistance. The wear surfaces were analyzed by SEM. Tests have shown that the addition of fiber does not affect the rate of abrasive wear of the original NR/CB rubber regardless of the grain size of the abrasive. Addition of modifiers that increase tensile modulus M10, hardness HSh, tear resistance TR, tensile strength A, and degree of crosslinking γ reduces the wear rate under friction on coarse abrasive, which is characteristic of abrasive wear with a predominance of micro-cutting. The greatest influence, judging by the value of the correlation coefficient, is exerted by the value of M10, dependent on the bond strength between the matrix and the fiber, which allows predicting the wear rate of rubbers based on the results of mechanical tests. When worn on a fine abrasive paper, the increase in M10, HSh, TR, and γ on the contrary, raises the wear rate of rubber, and the tensile toughness has practically no effect on it. This is attributed to the predominance of the fatigue wear mechanism, in which the wear rate increases with contact stresses, in proportion to the strength properties, with tear resistance exerting the greater effect on the wear rate.

Abstract Image

基于天然橡胶、炭黑和聚噁二唑纤维的橡胶的磨料磨损
摘要 研究了磨料粒度和改性剂(低分子量液体橡胶(LMWRs)、亚硫酰硅烷)对基于天然橡胶(NR)、炭黑(CB)和聚恶二唑(POD)纤维的橡胶磨耗纸磨损率的影响,并将其作为橡胶结构和机械性能的函数。在封闭式混合器中制备了模型橡胶混合物,在滚筒式机器上进行了磨料磨损试验,并通过 DMA、静态拉伸试验、硬度测量和抗撕裂性对橡胶的结构和机械性能进行了表征。用扫描电镜对磨损表面进行了分析。试验表明,无论磨料的粒度如何,纤维的添加都不会影响原始 NR/CB 橡胶的磨料磨损率。添加能提高拉伸模量 M10、硬度 HSh、抗撕裂性 TR、拉伸强度 A 和交联度 γ 的改性剂可降低粗磨料摩擦下的磨损率,这是以微切为主的磨料磨损的特征。从相关系数值来看,影响最大的是 M10 值,它取决于基体和纤维之间的结合强度,可以根据机械测试结果预测橡胶的磨损率。在细砂纸上磨损时,M10、HSh、TR 和 γ 的增加反而会提高橡胶的磨损率,而拉伸韧性几乎没有影响。这是因为疲劳磨损机制占主导地位,磨损率随接触应力的增加而增加,与强度特性成比例,抗撕裂性对磨损率的影响更大。
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来源期刊
Journal of Friction and Wear
Journal of Friction and Wear ENGINEERING, MECHANICAL-MATERIALS SCIENCE, MULTIDISCIPLINARY
CiteScore
1.50
自引率
28.60%
发文量
21
审稿时长
6-12 weeks
期刊介绍: Journal of Friction and Wear is intended to bring together researchers and practitioners working in tribology. It provides novel information on science, practice, and technology of lubrication, wear prevention, and friction control. Papers cover tribological problems of physics, chemistry, materials science, and mechanical engineering, discussing issues from a fundamental or technological point of view.
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