Silver and g-C3N4 co-modified biochar (Ag-CN@BC) for enhancing photocatalytic/PDS degradation of BPA: Role of carrier and photoelectric mechanism

Abstract

Photocatalytic property of nano Ag is weak and its enhancement is important to enlarge its application. Herein, a novel strategy of constructing silver g-C₃N₄ biochar composite (Ag-CN@BC) as photocatalyst is developed and its photocatalytic degradation of bisphenol A (BPA) coupled with peroxydisulfate (PDS) oxidation process is characterized. Characterization result showed that silver was evenly embedded into the g-C₃N₄ structure of the nitrogen atoms format, impeding agglomeration of Ag by distributing stably on biochar. In optimum condition, BPA of 10 mg/L could be degraded completely at pH of 9.0 with a 0.5 g/L photocatalyst, 2 mM PDS in Ag-CN@BC-2 (Ag/melamine molar ratio of 0.5)/PDS system (99.2%, k = 4.601 h⁻¹). Ag-CN@BC shows superior mineralization ratio in degrading BPA to CO₂ and H₂O via active radical way, including holes (h⁺), superoxide radicals (•O₂^⁻), sulfate radicals (SO₄•^⁻), and hydroxyl radicals (•OH). Proper amount of silver can be dispersed effectively by gC₃N₄, which is responsible for improving the visible-light absorbing capability and accelerate charge transfer during activation of PDS for BPA degradation, while biochar as carrier in the composite is supposed to enhance the photoelectric degradation of BPA by reducing the band gap and increasing the photocurrent of Ag-CN@BC catalyst. Ag-CN@BC exhibits excellent catalyst stability and photocatalytic activity for treatment of toxic organic contaminants in the environment.