Dissolution process and mechanism of montmorillonite in oxalic acid and sulfuric acid media at various pH levels

Abstract

The dissolution of silicate minerals plays a crucial role in many natural geological processes. In order to better comprehend the reaction mechanisms and dissolution characteristics of montmorillonite in different acidic systems, the effects of interfacial reactions of montmorillonite with oxalic and sulfuric acid solutions at various pH levels on the ionic dissolution, crystal structure, and micro-morphology were studied, and the morphology of aluminum and saturation index of secondary mineral were simulated. It was shown that the dissolution amounts of Mg²⁺, Al³⁺ and Si⁴⁺ in montmorillonite structure decreased with the increase of pH value, which reflected the dependence of montmorillonite dissolution on the pH value of solution. The dissolution percentages of Mg²⁺, Al³⁺ and Si⁴⁺ after the reaction of montmorillonite with oxalic acid solution were greater than those in sulfuric acid solution, and the highest dissolution rate of Al³⁺, indicated that both ligands and protons attacked the surface sites of montmorillonite and accelerated the dissolution of ions. Moreover, oxalate ligands exerted specific binding effects on Al³⁺ ions. While reacting with oxalate and sulfate, the tetrahedral, octahedral and interlayer cations of montmorillonite exhibited the non-stoichiometric and inconsistent dissolution. The oxalate ligands have a strong complexation effect on Al³⁺, so that Al³⁺ in oxalate solution exists in the form of aluminum oxalate complex, which reduces the effective concentration of Al³⁺ in solution and promotes the dissolution of Al³⁺ in montmorillonite structure. The Mg²⁺ ions settled at octahedral substitution sites possessed weak stability, while those from the interlayer featured strong interlayer interchangeability, demonstrating the dissolution percentage up to 10.85 % and 8.62 % even in oxalic and sulfuric acid solutions at pH of 6.5. All secondary mineral phases in the solution were undersaturated, making the montmorillonite dissolution difficult to balance. Montmorillonite has a high cation exchange capacity, which makes it have a strong buffer capacity to exogenous acids. This study helps to explain the dissolution process of montmorillonite in inorganic and organic acid solutions at different pH value.