Hesperidin and 5, 7-dimethoxycoumarin act as markers in the chemotaxonomy of Citrus medica L. var. sarcodactylis Swingle and Citrus medica L.

IF 16.4 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY
Di Wu , Miao-Miao Zhang , Hong-Ping Long , Xiao-Yuan Lin , Kai Liu
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Abstract

Citrus medica L. var. Sarcodactylis Swingle and C. medica L. were the subject of a chemotaxonomic inquiry using high-performance liquid chromatography (HPLC) fingerprint and multivariate data analysis, including hierarchical cluster analysis (HCA), principal component analysis (PCA), and orthogonal partial least squares-discriminant analysis (OPLS-DA). The results are in good agreement with current knowledge of the systematics of C. medica var. Sarcodactylis and C. medica. The analysis of Citri Sarcodactylis Fructus (CSF) and Citri Fructus (CF) showed that their chemical composition was highly similar except for the content; hesperidin (HP) and 5, 7-dimethoxycoumarin (DMC) were distinguishing markers for C. medica var. Sarcodactylis and C. medica; CSF had a significantly higher concentration of DMC than CF; additionally, the content ratio of HP to DMC in CSF was less than one (0.2401–0.7953), but in CF, it was more than one (2.5775–25.7800). The present work revealed the chemotaxonomic significance of HP and DMC for C. medica var. Sarcodactylis and C. medica and validated the traditional plant taxonomy regarding the two species at the chemical level.

Abstract Image

橙皮甙和5, 7-二甲氧基香豆素在柑橘变种sarcodactylis Swingle和Citrus medica L.的化学分类中起标记作用
利用高效液相色谱(HPLC)指纹图谱和多元数据分析,包括层次聚类分析(HCA)、主成分分析(PCA)和正交偏最小二乘判别分析(OPLS-DA),对柑橘属(Citrus medica L. var. Sarcodactylis Swingle)和枸橘属(C. medica L.)进行了化学分类学研究。结果与目前对 C. medica var.对柑橘果实(CSF)和柑橘果实(CF)的分析表明,除含量外,它们的化学成分高度相似;橙皮甙(HP)和 5,7-二甲氧基香豆素(DMC)是区分柑橘变种(C. medica var.此外,CSF 中 HP 与 DMC 的含量比小于 1(0.2401-0.7953),而 CF 中则大于 1(2.5775-25.7800)。本研究揭示了 HP 和 DMC 对 C. medica var.
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来源期刊
Accounts of Chemical Research
Accounts of Chemical Research 化学-化学综合
CiteScore
31.40
自引率
1.10%
发文量
312
审稿时长
2 months
期刊介绍: Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
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上海源叶 neohesperidin
上海源叶 limonin
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